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Synthesis of ultrasmall, homogeneously alloyed, bimetallic nanoparticles on silica supports

Wong, A., Liu, Q., Griffin, S., Nicholls, A., Regalbuto, J. R.·2017·Science

Abstract

Dispersing small, bimetallic nanoparticles: For applications of nanoparticles in sensing and catalysis, smaller nanoparticles are often more effective because they expose more active surface sites. The properties of metallic nanoparticles can also be improved by creating bimetallic alloys, but typical synthetic methods yield larger nanoparticles where the metals are poorly mixed. Wong et al. show that well-mixed bimetallic ∼1-nm-diameter nanoparticles can be made on silica supports. To do this, they exploited strong electrostatic adsorption, in which the metal precursors are strongly adsorbed onto the surface by controlling pH relative to the surface point of zero charge. Their method was successful for a wide range of metal alloys. Science , this issue p. 1427

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Research works printed but not linked: 17

  1. 10.1126/science.aad2204 · doi:10.1126/science.aad2204
  2. B. Zhou S. Hermans G. A. Somorjai Nanotechnology in Catalysis (Springer 2003) vol. 1. · doi:10.1007/978-1-4419-9048-8
  3. J. Regalbuto Catalyst Preparation: Science and Engineering (CRC Press 2016). · doi:10.1201/9781420006506
  4. J. H. Sinfelt J. Cusumano Bimetallic Catalysts (Academic Press 1977). · doi:10.1016/b978-0-12-147450-8.50006-x
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  9. 10.1039/C6CP05314A · doi:10.1039/c6cp05314a
  10. 10.1002/cctc.201402175 · DOI
  11. 10.1016/j.cattod.2014.09.029 · doi:10.1016/j.cattod.2014.09.029
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Metadata

Authors
Wong, A., Liu, Q., Griffin, S., Nicholls, A., & Regalbuto, J. R.
Venue
Science
Published
2017-12-15
Volume
358
Issue
6369
Pages
1427-1430
ISSN
  • 0036-8075 (ISSN-L)
  • 1095-9203
OpenAlex
W2768855432
Cited by
398
References
16
FWCI
13.55
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Synthesis of ultrasmall, homogeneously alloyed, bimetallic nanoparticles on silica supports. https://app.cochat.ai/papers/10.1126/science.aao6538
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Wong, A., Liu, Q., Griffin, S., Nicholls, A., & Regalbuto, J. R. (2017). Synthesis of ultrasmall, homogeneously alloyed, bimetallic nanoparticles on silica supports. Science. https://doi.org/10.1126/science.aao6538

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