The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Truly combining the advantages of polymeric and zeolite membranes for gas separations
Open accessAbstract
Mixed-matrix membranes (MMMs) have been investigated to render energy-intensive separations more efficiently by combining the selectivity and permeability performance, robustness, and nonaging properties of the filler with the easy processing, handling, and scaling up of the polymer. However, truly combining all in one single material has proven very challenging. In this work, we filled a commercial polyimide with ultrahigh loadings of a high–aspect ratio, CO 2 -philic Na-SSZ-39 zeolite with a three-dimensional channel system that precisely separates gas molecules. By carefully designing both zeolite and MMM synthesis, we created a gas-percolation highway across a flexible and aging-resistant (more than 1 year) membrane. The combination of a CO 2 -CH 4 mixed-gas selectivity of ~423 and a CO 2 permeability of ~8300 Barrer outperformed all existing polymer-based membranes and even most zeolite-only membranes.
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Cites
Effect of the damping function in dispersion corrected density functional theory
Grimme, S., Ehrlich, S., & Goerigk, L. (2011) · Journal of Computational Chemistry · doi:10.1002/jcc.21759 · Cited by 28,221
Seven chemical separations to change the world
Sholl, D. S., & Lively, R. P. (2016) · Nature · doi:10.1038/532435a · Cited by 4,769
Kühne, T. D., Iannuzzi, M., Del Ben, M., Rybkin, V. V., Seewald, P., Stein, F., Laino, T., Khaliullin, R. Z., Schütt, O., Schiffmann, F., et al. (2020) · The Journal of Chemical Physics · doi:10.1063/5.0007045 · Cited by 4,468
Carbon capture and storage update
Boot-Handford, M. E., Abanades, J. C., Anthony, E. J., Blunt, M. J., Brandani, S., Mac Dowell, N., Fernández, J. R., Ferrari, M.-C., Gross, R., Hallett, J. P., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42350f · Cited by 2,386
Discriminative Separation of Gases by a “Molecular Trapdoor” Mechanism in Chabazite Zeolites
Shang, J., Li, G., Singh, R., Gu, Q., Nairn, K. M., Bastow, T. J., Medhekar, N., Doherty, C. M., Hill, A. J., Liu, J. Z., et al. (2012) · Journal of the American Chemical Society · doi:10.1021/ja309274y · Cited by 436
Improved SAPO‐34 Membranes for CO2/CH4 Separations
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Carbon Dioxide and Nitrogen Adsorption on Cation-Exchanged SSZ-13 Zeolites
Pham, T. D., Liu, Q., & Lobo, R. F. (2013) · Langmuir · doi:10.1021/la304138z · Cited by 186
Cited by
Chen, G., Liu, G., Pan, Y., Liu, G., Gu, X., Jin, W., & Xu, N. (2023) · Chemical Society Reviews · doi:10.1039/d3cs00370a · Cited by 269
Metadata
- Authors
- Tan, X., Robijns, S., Thür, R., Ke, Q., De Witte, N., Lamaire, A., Li, Y., Aslam, I., Van Havere, D., Donckels, T., Van Assche, T., Van Speybroeck, V., Dusselier, M., & Vankelecom, I.
- Venue
- Science
- Published
- 2022-12-16
- Volume
- 378
- Issue
- 6625
- Pages
- 1189-1194
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W4311551606
- Cited by
- 205
- References
- 7
- FWCI
- 14.58
- Type
- journal article
- Language
- en
- Open access
- green
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- Tan, X., Robijns, S., Thür, R., Ke, Q., De Witte, N., Lamaire, A., Li, Y., Aslam, I., Van Havere, D., Donckels, T., Van Assche, T., Van Speybroeck, V., Dusselier, M., & Vankelecom, I. (2022). Truly combining the advantages of polymeric and zeolite membranes for gas separations. Science. https://doi.org/10.1126/science.ade1411
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