Carbon Dioxide and Nitrogen Adsorption on Cation-Exchanged SSZ-13 Zeolites
Abstract
Samples of high-silica SSZ-13, ion exchanged with protons and alkali-metal cations Li(+), Na(+), and K(+), were investigated using adsorption isotherms of CO(2) and N(2). The results show that Li-, Na-SSZ-13 have excellent CO(2) capacity at ambient temperature and pressure; in general, Li-SSZ-13 shows the highest capacity for N(2), CO(2) particularly in the low-pressure region. The effect of cation type and Si/Al ratio (6 and 12) on the adsorption properties was investigated through analysis of adsorption isotherms and heats of adsorption. The separation of CO(2) in a flue gas mixture was evaluated for these adsorbents in the pressure swing adsorption and vacuum pressure adsorption processes.
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Materials such as SAPO-RHO (RHO), NaTEA-PST-20, Li-SSZ-13-6, Na-SSZ-13-6 (CHA), or SAPO-56 (AFX) present promising values of selectivities (>10) and working capacities (ca. 0.5 mmol/g) at relevant conditions, comparable with traditional 5A and 13X zeolites.
“Materials, such as SAPO-RHO (RHO),507 NaTEA-PST-20,275 Li-SSZ-13–6, Na-SSZ-13–6 (CHA),555 or SAPO-56 (AFX)507 present promising values of selectivities (>10) and working capacities (ca. 0.5 mmol/g) at relevant conditions, comparable with those of traditional 5A521 and 13X522 zeolites.”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [555]
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- Authors
- Pham, T. D., Liu, Q., & Lobo, R. F.
- Affiliations
- University of Delaware (US)
- Center for Catalytic Science and Technology, Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy Street, Newark, Delaware 19716, United States
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-12-31
- Volume
- 29
- Issue
- 2
- Pages
- 832-839
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2320178227
- Cited by
- 186
- References
- 49
- Citations by year
- 2026: 9 · 2025: 18 · 2024: 12 · 2023: 16 · 2022: 13 · 2021: 14 · 2020: 14 · 2019: 17 · 2018: 18 · 2017: 16 · 2016: 8 · 2015: 12 · 2014: 14 · 2013: 5
- FWCI
- 15.16
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Langmuir (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Science Foundation
- Vietnam Education Foundation
- Division of Chemical, Bioengineering, Environmental, and Transport Systems
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Chemistry › Spectroscopy › Adsorption, diffusion, and thermodynamic properties of materials
- Keywords
- SSZ-13 zeolite, cation exchange, CO2 adsorption, nitrogen adsorption, sodium-exchanged zeolite, Si/Al ratio, heat of adsorption, pressure swing adsorption, high-silica zeolites
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