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Cited by 74Adsorption, diffusion, and thermodynamic properties of materialsHydrogen Storage and MaterialsMembrane Separation and Gas Transport

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

ADSORPTION EQUILIBRIA OF HYDROGEN, DEUTERIUM, AND THEIR MIXTURES. PART I

Basmadjian, D.·1960·Canadian Journal of Chemistry
DOI 10.1139/v60-016
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Abstract

Adsorption isotherms of hydrogen and deuterium have been measured at temperatures of 75–90 °K and pressures up to 760 mm Hg on the following six adsorbents: charcoal (2), silica gel, and Linde molecular sieves type 4A, 5A, and 13X.Deuterium was found to be adsorbed to a greater extent than hydrogen in all cases investigated, its isosteric heat of adsorption exceeding that of hydrogen by 50 to 300 cal/mole.Binary adsorption isotherms were determined on the same adsorbents in the range 10–90% D 2 at temperatures of 75 and 90 °K and a total pressure π of 750 and 200 mm Hg. The analyses were performed by the thermal conductivity method using thermistor sensing elements in a static system at atmospheric pressure. The device proved of exceptional stability, requiring no recalibrations and yielding an analytical accuracy of better than 0.02% deuterium content. The binary separation factors α were found to be constant over the concentration range investigated, with values for α varying from about 1.25 on charcoal to 2.54 on type 4A molecular sieves at 75 °K and 750 mm Hg. The results suggest that the variations in α are due mainly to differences in chemical composition of the adsorbents rather than pore size, surface area, or origin of the materials.

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  • According to prior studies, heavier hydrogen isotopes were more strongly adsorbed than lighter isotopes, mainly due to their larger heats of adsorption, and no remarkable influence of pore size was observed, not even in microporous adsorbents.

    “According to these studies, the heavier isotopes were more strongly adsorbed than the lighter isotopes, mainly due to their larger heats of adsorption, and no remarkable influence of the pore size was observed, not even in microporous adsorbents.399,402,403”

    From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [402]

  • Separation-oriented adsorption studies of hydrogen isotopes on activated carbons, silicas, and zeolites have been reported since the 1930s.

    “Separation-oriented adsorption studies of hydrogen isotopes on activated carbons, silicas, and zeolites have been reported since the 1930s by several authors.398−404”

    From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [402]

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Research works printed but not linked: 20

  1. GLUECICAUF E., 1949, Discissions 1:araday Soc., 7, 199
  2. MELICONIAN G. A., 1954, Z. Elektrochern., 58, 616
  3. EDSE R., 1940, Chem., 53, 210
  4. WHITE D., 1959, J. Chem. Phys., 27, 1368, 10.1063/1.1730203 · DOI · Paper page
  5. PETERS,R. and LOHMAR, \V. Doklady .Alcad. Naulc S.S.S.R. 57, 157 (1947).
  6. 1937, Chem. A, 180, 51
  7. GOULD A. J., 1934, J . Chern. Phys., 2, 362, 10.1063/1.1749490 · DOI · Paper page
  8. THOMAS C., 1959, Phys. Chern., 63, 427, 10.1021/j150573a021 · DOI
  9. OHROSHI S., 1958, J . Chem. Soc. Japan, 31, 770, 10.1246/bcsj.31.770 · DOI
  10. FARKAS,A. Orthohydrogen, parahydrogen and heavy hydrogen. The University Press, Cambridge, Eng. 1935.
  11. SACHSSE,13. and B A T % L E < I< Z.physik. Chem. rl, 171, 331 (1934). · DOI
  12. GROSS P., 1933, Mikrochemie, 17, 43, 10.1007/BF02740117 · DOI
  13. TRENNER N. R., 1937, Chem. Phys., 5, 382
  14. SANDLER, Y . C. J . Phys. dhem. 58,<58(1954). ' · DOI
  15. CUNNINGHALL C. M., J . rl, 11
  16. BURSTEIK R., 1938, Physicochim U. R. S. S., 8, 857
  17. 1939, TAN DER WAARDEN. Physica, 6, 49
  18. M. and SCHEFFER.F. E. C. Rec. tray. chim. 71. 689 (1952). · DOI
  19. BARRER R. M., 1959, Brit. Chern. Eng., 4, 267
  20. VAN CLEAVE A. B., 1935, Research, 12, 57

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Metadata

Authors
Basmadjian, D.
Corresponding author
Basmadjian, D.
Venue
Canadian Journal of Chemistry
Publisher
Canadian Science Publishing
Published
1960-01-01
Volume
38
Issue
1
Pages
141-148
ISSN
  • 0008-4042 (ISSN-L)
  • 1480-3291
DOI
10.1139/v60-016
OpenAlex
W1990930570
Cited by
74
References
1
Citations by year
2025: 2 · 2022: 3 · 2020: 3 · 2019: 2 · 2018: 2 · 2017: 3 · 2016: 1 · 2014: 1 · 2013: 1
FWCI
0.74
Type
journal article
Language
en
Open access
closed
Licence
www.nrcresearchpress.com/page/about/CorporateTextAndDataMining (tdm)
Locations
Canadian Journal of Chemistry (publishedVersion)
Topics
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Adsorption, diffusion, and thermodynamic properties of materials
  • Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
  • Physical Sciences › Chemical Engineering › Filtration and Separation › Membrane Separation and Gas Transport
Keywords
hydrogen adsorption, deuterium adsorption, hydrogen-deuterium mixtures, adsorption isotherms, isosteric heat of adsorption, charcoal, silica gel, molecular sieves, cryogenic adsorption

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