Shear, Friction, and Lubrication Forces Between Polymer-Bearing Surfaces
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At highest compressions (D < ca. Rg), the entropic effect suppressing interpenetration becomes negligible.
“At the highest compressions, however, when the surface separation becomes comparable with or smaller than the radius of gyration of the polymer chains ( D < ca. R g ), one expects the entropic effect suppressing the interpenetration to become negligible [20, 27].”
From Hydration lubrication (2013) · cites this paper as [20]
Opposing brush molecules interpenetrate only very weakly when compressed, due to entropic factors.
“This occurs because, as a result of entropic factors, the opposing brush molecules interpenetrate only very weakly when compressed [20, 26, 27]: It is energetically favourable for two swollen brushes on initial compression to become less swollen and denser than to interpenetrate each other.”
From Hydration lubrication (2013) · cites this paper as [20]
It is energetically favourable for two swollen brushes on initial compression to become less swollen and denser than to interpenetrate each other.
“This occurs because, as a result of entropic factors, the opposing brush molecules interpenetrate only very weakly when compressed [20, 26, 27]: It is energetically favourable for two swollen brushes on initial compression to become less swollen and denser than to interpenetrate each other.”
From Hydration lubrication (2013) · cites this paper as [20]
The thickness d of the overlapped region of two brushes in the moderate compression regime varies only very weakly with compression.
“It may be shown [20, 27] that the thickness d of the overlapped region of the two brushes in the moderate compression regime varies only very weakly with the compression:”
From Hydration lubrication (2013) · cites this paper as [20]
The citation lists haven’t been fetched yet
Cited by 413
- Authors
- Klein, J.
- Corresponding author
- Klein, J
- ORCID
- Klein, J
- Venue
- Annual Review of Materials Science
- Publisher
- Annual Reviews
- Published
- 1996-08
- Volume
- 26
- Issue
- 1
- Pages
- 581-612
- ISSN
- 0084-6600 (ISSN-L)
- OpenAlex
- W2038533195
- Cited by
- 413
- References
- 0
- Citations by year
- 2026: 10 · 2025: 5 · 2024: 4 · 2023: 15 · 2022: 8 · 2021: 10 · 2020: 7 · 2019: 16 · 2018: 13 · 2017: 14 · 2016: 12 · 2015: 14 · 2014: 21 · 2013: 24 · 2012: 24
- FWCI
- 18.61
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Annual Review of Materials Science (publishedVersion)
- Topics
- Physical Sciences › Engineering › Mechanics of Materials › Tribology and Wear Analysis
- Physical Sciences › Engineering › Mechanics of Materials › Adhesion, Friction, and Surface Interactions
- Physical Sciences › Engineering › Mechanical Engineering › Tribology and Lubrication Engineering
- Keywords
- shear force, friction, lubrication, polymer tribology, polymer bearings
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