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Nucleation: Measurements, Theory, and Atmospheric Applications
Abstract
New experiments have succeeded in measuring actual rates of nucleation and are revealing the shortcomings of classical nucleation theory, which assumes that the molecular-scale regions of the new phase may be treated using bulk thermodynamics and planar surface free energies. In response to these developments, new theories have been developed that incorporate information about molecular interactions in a more realistic fashion. This article reviews recent experimental and theoretical advances in the study of nucleation of liquids from the vapor and of crystals from the melt, with particular emphasis on phenomena that relate to particle formation in the atmosphere.
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Citations
Cited by
Formation Mechanisms of Uniform Nanocrystals via Hot‐Injection and Heat‐Up Methods
Kwon, S. G., & Hyeon, T. (2011) · Small · doi:10.1002/smll.201002022 · Cited by 677
Dense Liquid Precursor for the Nucleation of Ordered Solid Phases from Solution
Vekilov, P. G. (2004) · Crystal Growth & Design · doi:10.1021/cg049977w · Cited by 502
Mechanistic Insights into the Crystallization of Amorphous Calcium Carbonate (ACC)
Bots, P., Benning, L. G., Rodriguez-Blanco, J.-D., Roncal-Herrero, T., & Shaw, S. (2012) · Crystal Growth & Design · doi:10.1021/cg300676b · Cited by 474
Finney, E. E., & Finke, R. G. (2008) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2007.05.092 · Cited by 377
Confinement or the Nature of the Interface? Dynamics of Nanoscopic Water
Moilanen, D. E., Levinger, N. E., Spry, D. B., & Fayer, M. D. (2007) · Journal of the American Chemical Society · doi:10.1021/ja073977d · Cited by 259
Metadata
- Authors
- Laaksonen, A., Talanquer, V., & Oxtoby, D. W.
- Venue
- Annual Review of Physical Chemistry
- Publisher
- Annual Reviews
- Published
- 1995-10
- Volume
- 46
- Issue
- 1
- Pages
- 489-524
- ISSN
- 0066-426X (ISSN-L)
- 1545-1593
- OpenAlex
- W2171252090
- Cited by
- 388
- References
- 0
- FWCI
- 9.88
- Type
- journal article
- Language
- en
- Open access
- closed
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- Laaksonen, A., Talanquer, V., & Oxtoby, D. W. (1995). Nucleation: Measurements, Theory, and Atmospheric Applications. Annual Review of Physical Chemistry. https://doi.org/10.1146/annurev.pc.46.100195.002421
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.