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Cited by 1,198Spectroscopy and Quantum Chemical StudiesLaser-Matter Interactions and ApplicationsPhotochemistry and Electron Transfer Studies

The DOI matches its Crossref record; 131 of the 133 references it cites were found in a registry or an index.

Two-Dimensional Femtosecond Spectroscopy

Jonas, David M.·2003·Annual Review of Physical Chemistry
DOI 10.1146/annurev.physchem.54.011002.103907
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Abstract

▪ Abstract The simplest two-dimensional (2D) spectra show how excitation with one (variable) frequency affects the spectrum at all other frequencies, thus revealing the molecular connections between transitions. Femtosecond 2D Fourier transform (2D FT) spectra are more flexible and share some of the remarkable properties of their conceptual parent, 2D FT nuclear magnetic resonance. When 2D FT spectra are experimentally separated into real absorptive and imaginary refractive parts, the time resolution and frequency resolution can both reach the uncertainty limit set for each resonance by the sample itself. Coherent four-level contributions to the signal provide new molecular phase information, such as relative signs of transition dipoles. The nonlinear response can be picked apart by selecting a single coherence pathway (e.g., specifying the relative signs of energy level difference frequencies during different time intervals as in the photon echo). Because molecules are frozen on the femtosecond timescale, femtosecond 2D FT experiments can separate a distribution of instantaneous molecular environments and intramolecular geometries as inhomogeneous broadening. This review provides an introduction to two-dimensional Fourier transform experiments exploiting second- and third-order vibrational and electronic nonlinearities.

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Research works printed but not linked: 7

  1. Bodenhausen G, 1978, J. Magn. Reson., 31, 75
  2. Ulness DJ, Kirkwood JC, Albrecht AC. 2001. Raman spectrscopy. In Encyclopedia of Chemical Physics and Physical Chemistry Vol II: Methods , ed. JH Moore, ND Spencer, pp. 1017–62. Philadelphia: Inst. Phys.
  3. Ge NH, 2002, Phys. Chem. Comm., 3, 17
  4. Siegman AE, 1986, Lasers.
  5. Yariv A, 1975, Quantum Electronics.
  6. Vaccaro PH. 1997. Degenerate four-wave mixing (DFWM) spectroscopy. In Nonlinear Spectroscopy for Molecular Structure Determination , ed. RW Field, E Hirota, JP Maier, S Tsuchiya, pp. 75–126. Oxford: Blackwell Sci.
  7. Lepetit L, Joffre M, Cheriaux G, Migus A, Hulin D. 1995. Two dimensional nonlinear optics using femtosecond spectral interferometry. In Quantum Electronics and Laser Science , Vol. 16. p. 147. Washington, D.C.: Opt. Soc. Am.

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Metadata

Authors
Jonas, D. M.
Affiliations
University of Colorado Boulder (US)
Corresponding author
Jonas, David M.
ORCID
Jonas, David M.
Venue
Annual Review of Physical Chemistry
Publisher
Annual Reviews
Published
2003-10
Volume
54
Issue
1
Pages
425-463
ISSN
  • 0066-426X (ISSN-L)
  • 1545-1593
DOI
10.1146/annurev.physchem.54.011002.103907
OpenAlex
W2105576535
Cited by
1,198
References
133
Citations by year
2026: 43 · 2025: 60 · 2024: 54 · 2023: 47 · 2022: 45 · 2021: 55 · 2020: 59 · 2019: 65 · 2018: 57 · 2017: 74 · 2016: 44 · 2015: 54 · 2014: 50 · 2013: 60 · 2012: 46
FWCI
1.96
Type
journal article
Language
en
Open access
closed
Locations
  • Annual Review of Physical Chemistry (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Spectroscopy and Quantum Chemical Studies
  • Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Laser-Matter Interactions and Applications
  • Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
Keywords
two-dimensional spectroscopy, femtosecond spectroscopy, electronic nonlinearity, photon echo, inhomogeneous broadening, nonlinear optical properties

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