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Preparation of Novel Room-Temperature Molten Salts by Neutralization of Amines
Abstract
Examples of a new class of onium salts bearing the tetrafluoroborate anion ( BF 4 − ) were prepared by neutralization of the corresponding amines. This method greatly simplifies the preparation of many organic molten salts. Some of the resulting neutralized amines displayed an ionic conductivity greater than 10 − 2 S cm − 1 at room temperature. The largest ionic conductivity was observed in 2‐methyl‐1‐pyrroline neutralized by HBF 4 . In addition, the ionic conductivity above the melting point is well described by the Vogel‐Tamman‐Fulcher formula. There is a correlation between the ionic conductivity of neutralized amines and of the corresponding alkylated onium salts having the same heteroaromatic rings. These neutralized amines are convenient models of onium salts having high ionic conductivity. © 2000 The Electrochemical Society. All rights reserved.
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Citations
Cited by
Application of ionic liquids to the electrodeposition of metals
Abbott, A. P., & McKenzie, K. J. (2006) · Physical Chemistry Chemical Physics · doi:10.1039/b607329h · Cited by 817
Ohno, H., & Fukumoto, K. (2007) · Accounts of Chemical Research · doi:10.1021/ar700053z · Cited by 631
Self-citationTemperature dependence of viscosity for room temperature ionic liquids
Okoturo, O. O., & VanderNoot, T. J. (2004) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2003.12.050 · Cited by 417
Ionic Liquids for Electrochemical Devices
HAGIWARA, R., & LEE, J. S. (2007) · Electrochemistry · doi:10.5796/electrochemistry.75.23 · Cited by 174
Metadata
- Authors
- Hirao, M., Sugimoto, H., & Ohno, H.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2000
- Volume
- 147
- Issue
- 11
- Pages
- 4168
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2029267359
- Cited by
- 215
- References
- 0
- FWCI
- 4.96
- Type
- journal article
- Language
- en
- Open access
- closed
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