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Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries
Abstract
The structure, synthesis, and electrochemical behavior of layered Li [ Ni x Li ( 1 / 3 − 2 x / 3 ) Mn ( 2 / 3 − x / 3 ) ] O 2 for x = 1 / 3 , 5/12, and 1/2 are reported for the first time. Li [ Ni x Li ( 1 / 3 − 2 x / 3 ) Mn ( 2 / 3 − x / 3 ) ] O 2 is derived from Li 2 MnO 3 or Li [ Li 1 / 3 Mn 2 / 3 ] O 2 by substitution of Li + and Mn 4 + by Ni 2 + while maintaining all the remaining Mn atoms in the 4+ oxidation state. Li [ Ni x Li ( 1 / 3 − 2 x / 3 ) Mn ( 2 / 3 − x / 3 ) ] O 2 with x = 5 / 12 can deliver steady capacities of 150 and 160 mAh/g at 30 and 55°C, respectively, between 3.0 and 4.4 V using a current density of 30 mA/g. Differential scanning calorimetry experiments on charged electrodes of Li [ Ni x Li ( 1 / 3 − 2 x / 3 ) Mn ( 2 / 3 − x / 3 ) ] O 2 for x = 5 / 12 indicate that this material should be safer than LiCoO 2 . Li [ Ni x Li ( 1 / 3 − 2 x / 3 ) Mn ( 2 / 3 − x / 3 ) ] O 2 with x = 1 / 3 , 5/12, and 1/2 can be cycled between 2.0 and 4.6 V to give capacities of about 200, 180, and 160 mAh/g, respectively, at 30°C. Li [ Ni x Li ( 1 / 3 − 2 x / 3 ) Mn ( 2 / 3 − x / 3 ) ] O 2 with x = 1 / 3 gives a capacity of 220 mAh/g at 55°C between 2.0 and 4.6 V using a current density of 30 mA/g. © 2001 The Electrochemical Society. All rights reserved.
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Cited by
Challenges Facing Lithium Batteries and Electrical Double‐Layer Capacitors
Choi, N., Chen, Z., Freunberger, S. A., Ji, X., Sun, Y., Amine, K., Yushin, G., Nazar, L. F., Cho, J., & Bruce, P. G. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201201429 · Cited by 2,700
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries
Kang, K., Meng, Y. S., Bréger, J., Grey, C. P., & Ceder, G. (2006) · Science · doi:10.1126/science.1122152 · Cited by 2,638
An, S. J., Li, J., Daniel, C., Mohanty, D., Nagpure, S., & Wood, D. L. (2016) · Carbon · doi:10.1016/j.carbon.2016.04.008 · Cited by 2,121
The development and future of lithium ion batteries
Blomgren, G. E. (2017) · Journal of The Electrochemical Society · doi:10.1149/2.0251701jes · Cited by 1,940
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Metadata
- Authors
- Lu, Z., MacNeil, D. D., & Dahn, J. R.
- Venue
- Electrochemical and Solid-State Letters
- Publisher
- The Electrochemical Society
- Published
- 2001
- Volume
- 4
- Issue
- 11
- Pages
- A191
- ISSN
- 1099-0062 (ISSN-L)
- OpenAlex
- W2232898241
- Cited by
- 941
- References
- 0
- FWCI
- 36.38
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lu, Z., MacNeil, D. D., & Dahn, J. R. (2001). Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries. Electrochemical and Solid-State Letters. https://doi.org/10.1149/1.1407994
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