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Electrochemical Properties of Lithium Vanadium Phosphate as a Cathode Material for Lithium-Ion Batteries
Abstract
The properties of the monoclinic lithium vanadium phosphate Li 3 V 2 ( PO 4 ) 3 are investigated using X-ray diffraction (XRD) and electrochemical methods. Electrochemical measurements conducted in half-cells with Li 3 V 2 ( PO 4 ) 3 as the cathode material and lithium metal as the anode have shown that this material exhibits an excellent reversibility when the charge extracted is confined to that equivalent to two lithiums per formula unit. The extraction of the last lithium is observed at a potential greater than 4.6 V vs . Li / Li + and involves a significant overvoltage. Upon discharge, however, XRD has shown that the original structure is recovered. © 2002 The Electrochemical Society. All rights reserved.
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Cited by
Li3V2(PO4)3 cathode materials for lithium-ion batteries: A review
Rui, X., Yan, Q., Skyllas-Kazacos, M., & Lim, T. M. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.01.126 · Cited by 342
Some transition metal (oxy)phosphates and vanadium oxides for lithium batteries
Whittingham, M. S., Song, Y., Lutta, S., Zavalij, P. Y., & Chernova, N. A. (2005) · Journal of Materials Chemistry · doi:10.1039/b501961c · Cited by 296
A Na3V2(PO4)3 cathode material for use in hybrid lithium ion batteries
Song, W., Ji, X., Pan, C., Zhu, Y., Chen, Q., & Banks, C. E. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp52308j · Cited by 126
Metadata
- Authors
- Saı̈di, M. Y., Barker, J., Huang, H., Swoyer, J. L., & Adamson, G.
- Venue
- Electrochemical and Solid-State Letters
- Publisher
- The Electrochemical Society
- Published
- 2002
- Volume
- 5
- Issue
- 7
- Pages
- A149
- ISSN
- 1099-0062 (ISSN-L)
- OpenAlex
- W2089598696
- Cited by
- 245
- References
- 0
- FWCI
- 6.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Electrochemical Properties of Lithium Vanadium Phosphate as a Cathode Material for Lithium-Ion Batteries. https://app.cochat.ai/papers/10.1149/1.1479295
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- Saı̈di, M. Y., Barker, J., Huang, H., Swoyer, J. L., & Adamson, G. (2002). Electrochemical Properties of Lithium Vanadium Phosphate as a Cathode Material for Lithium-Ion Batteries. Electrochemical and Solid-State Letters. https://doi.org/10.1149/1.1479295
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