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Rechargeable Lithium Sulfur Battery
Abstract
This paper reports on the investigation of rate capability and cycle characteristics of a lithium sulfur battery. The second discharge region where solid is formed on the surface of the carbon matrix in the cathode was highly sensitive to cathode thickness and discharge rate. The scanning electron microscope (SEM) observation suggests that thick layer formed at the surface of the cathode causes the diminution of the second discharge region at high discharge rate. Upon repeated cycle, the delocalization of the surface layer happened, however, the irreversible gradually increased with cycle as evidence by (SEM) and wave dispersive spectroscopy measurements, causing capacity fade. The formation of the irreversible was more significant for higher rates of discharge. It is believed that the destruction of the carbon matrix by stress generated during the localized deposition of is responsible for the formation of irreversible © 2003 The Electrochemical Society. All rights reserved.
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Citations
Cited by
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Lithium Batteries: Status, Prospects and Future
Scrosati, B., & Garche, J. (2010) · Journal of Power Sources · doi:10.1016/j.jpowsour.2009.11.048 · Cited by 5,153
Rechargeable Lithium–Sulfur Batteries
Manthiram, A., Fu, Y., Chung, S.-H., Zu, C., & Su, Y.-S. (2014) · Chemical Reviews · doi:10.1021/cr500062v · Cited by 4,665
Challenges Facing Lithium Batteries and Electrical Double‐Layer Capacitors
Choi, N., Chen, Z., Freunberger, S. A., Ji, X., Sun, Y., Amine, K., Yushin, G., Nazar, L. F., Cho, J., & Bruce, P. G. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201201429 · Cited by 2,700
Self-citationChallenges and Prospects of Lithium–Sulfur Batteries
Manthiram, A., Fu, Y., & Su, Y.-S. (2013) · Accounts of Chemical Research · doi:10.1021/ar300179v · Cited by 2,380
Metadata
- Authors
- Cheon, S.-E., Ko, K.-S., Cho, J.-H., Kim, S.-W., Chin, E.-Y., & Kim, H.-T.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2003
- Volume
- 150
- Issue
- 6
- Pages
- A800
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W1503411567
- Cited by
- 424
- References
- 0
- FWCI
- 2.68
- Type
- journal article
- Language
- en
- Open access
- closed
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- Cheon, S.-E., Ko, K.-S., Cho, J.-H., Kim, S.-W., Chin, E.-Y., & Kim, H.-T. (2003). Rechargeable Lithium Sulfur Battery. Journal of The Electrochemical Society. https://doi.org/10.1149/1.1571533
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
