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A Polymer Electrolyte‐Based Rechargeable Lithium/Oxygen Battery
Open accessAbstract
A novel rechargeable battery is reported. It comprises a conductive organic polymer electrolyte membrane sandwiched by a thin Li metal foil anode, and a thin carbon composite electrode on which oxygen, the electroactive cathode material, accessed from the environment, is reduced during discharge to generate electric power. It features an all solid state design in which electrode and electrolyte layers are laminated to form a 200 to 300 μm thick battery cell. The overall cell reaction during discharge appears to be . It has an open‐circuit voltage of about 3 V, and a load voltage that spans between 2 and 2.8 V depending upon the load resistance. The cell can be recharged with good coulombic efficiency using a cobalt phthalocyanine catalyzed carbon electrode.
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Citations
Cited by
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Electrical energy storage for the grid: A battery of choices
Dunn, B., Kamath, H., & Tarascon, J.-M. (2011) · Science · doi:10.1126/science.1212741 · Cited by 15,072
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
Rechargeable Batteries for Grid Scale Energy Storage
Zhu, Z., Jiang, T., Ali, M., Meng, Y., Jin, Y., Cui, Y., & Chen, W. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00289 · Cited by 1,769
Metadata
- Authors
- Abraham, K. M., & Jiang, Z.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1996-01-01
- Volume
- 143
- Issue
- 1
- Pages
- 1-5
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2097174687
- Cited by
- 2,092
- References
- 0
- FWCI
- 3.40
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Abraham, K. M., & Jiang, Z. (1996). A Polymer Electrolyte‐Based Rechargeable Lithium/Oxygen Battery. Journal of The Electrochemical Society. https://doi.org/10.1149/1.1836378
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
