The DOI matches its Crossref record.
Electrochemical Oxidation of Glucose on Single Crystal and Polycrystalline Gold Surfaces in Phosphate Buffer
Open accessAbstract
The electrochemical oxidation of glucose has been studied in phosphate buffer (pH = 7.4) on single crystal and polycrystalline gold electrodes using electrochemical techniques, ex situ NMR, in situ FTIR spectroscopy, and isotope labeling. Under these conditions, the results indicate that the rate determining step for the electro‐oxidation of glucose is bond breaking between the hydrogen atom and the carbon atom. Gluconolactone appears to be an intermediate and sodium gluconate is the reaction product. First order kinetics with respect to glucose were also found. Gold would be a useful electrode for sensor applications, if the inhibition of the glucose oxidation by the adsorption of could be avoided.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Recent advances in electrochemical non-enzymatic glucose sensors – A review
Hwang, D.-W., Lee, S., Seo, M., & Chung, T. D. (2018) · Analytica Chimica Acta · doi:10.1016/j.aca.2018.05.051 · Cited by 788
Non-enzymatic electrochemical sensing of glucose
Wang, G., He, X., Wang, L., Gu, A., Huang, Y., Fang, B., Geng, B., & Zhang, X. (2013) · Microchimica Acta · doi:10.1007/s00604-012-0923-1 · Cited by 522
Advances in non-enzymatic glucose sensors based on metal oxides
Zhu, H., Li, L., Zhou, W., Shao, Z., & Chen, X. (2016) · Journal of Materials Chemistry B · doi:10.1039/c6tb02037b · Cited by 473
Mechanism of glucose electrochemical oxidation on gold surface
Pasta, M., La Mantia, F., & Cui, Y. (2010) · Electrochimica Acta · doi:10.1016/j.electacta.2010.04.069 · Cited by 331
Combinatorial Discovery of Alloy Electrocatalysts for Amperometric Glucose Sensors
Sun, Y., Buck, H., & Mallouk, T. E. (2001) · Analytical Chemistry · doi:10.1021/ac0015117 · Cited by 306
Metadata
- Authors
- Hsiao, M. W., Adžić, R. R., & Yeager, E. B.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1996-03-01
- Volume
- 143
- Issue
- 3
- Pages
- 759-767
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W1982832557
- Cited by
- 240
- References
- 0
- FWCI
- 2.43
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Electrochemical Oxidation of Glucose on Single Crystal and Polycrystalline Gold Surfaces in Phosphate Buffer. https://app.cochat.ai/papers/10.1149/1.1836536
- The paper
- Hsiao, M. W., Adžić, R. R., & Yeager, E. B. (1996). Electrochemical Oxidation of Glucose on Single Crystal and Polycrystalline Gold Surfaces in Phosphate Buffer. Journal of The Electrochemical Society. https://doi.org/10.1149/1.1836536
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
