Cited by 92Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesAdvanced Battery Technologies Research

Ethylmethylcarbonate, a Promising Solvent for Li‐Ion Rechargeable Batteries

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Ein‐Eli, Yair, Thomas, Stacey R., Koch, Victor, Aurbach, Doron, Markovsky, Boris, Schechter, Alexander·1996·Journal of The Electrochemical Society

Abstract

Ethylmethylcarbonate (EMC) has been found to be a promising solvent for rechargeable Li‐ion batteries. Graphite electrodes, which are usually sensitive to the composition of the electrolyte solution, can be successfully cycled at high reversible capacities in several Li salt solutions in this solvent ( , etc.). These results are interesting because lithium ions cannot intercalate into graphite in diethyl carbonate solutions and cycle poorly in dimethyl carbonate solutions. To understand the high compatibility of EMC for Li‐ion battery systems as compared with the other two open‐chain alkyl carbonates mentioned above, the surface chemistry developed in both Li and carbon electrodes in EMC solution was studied and compared with that developed on these electrodes in other alkyl carbonate solutions. Basically, the major surface species formed on both electrodes in EMC include ROLi, , and species. The uniqueness of EMC as a battery solvent is discussed in light of these studies.

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Research works printed but not linked: 12

  1. E. Peled, in Proceedings of the Symposium on Li and Li Ion Batteries, S. Megahed Editor, PV 95-5, p.1, The Electrochemical Society Proceedings Series, Pennington, NJ (1995).
  2. F. Peled, in Lithium Batteries, J. R Gabano, Editor, Chap. 3, Academic Press, New York and London (1983).
  3. D. Aurbach, O.Youngman Chusid, Y. Carmeli, M. Babai, and V. Em-Eli, J. Power Sources, 43,47 (1993).
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Authors
Ein‐Eli, Y., Thomas, S. R., Koch, V., Aurbach, D., Markovsky, B., & Schechter, A.
Affiliations
Bar-Ilan University (IL)
Venue
Journal of The Electrochemical Society
Published
1996-12-01
Volume
143
Issue
12
Pages
L273-L277
ISSN
  • 0013-4651 (ISSN-L)
  • 1945-7111
OpenAlex
W2063401864
Cited by
92
References
0
Citations by year
2025: 1 · 2024: 5 · 2023: 1 · 2022: 1 · 2021: 2 · 2020: 4 · 2019: 5 · 2018: 5 · 2017: 5 · 2016: 2 · 2015: 2 · 2014: 1 · 2013: 2 · 2012: 2
FWCI
6.79
Type
journal article
Language
en
Open access
Locations
Journal of The Electrochemical Society (publishedVersion)
Funders
Office of Naval Research
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
  • Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
Keywords
lithium-ion battery electrolytes, graphite electrodes, lithium salt electrolytes, electrode surface chemistry, lithium intercalation, diethyl carbonate, dimethyl carbonate, reversible capacity

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