Ethylmethylcarbonate, a Promising Solvent for Li‐Ion Rechargeable Batteries
Open accessAbstract
Ethylmethylcarbonate (EMC) has been found to be a promising solvent for rechargeable Li‐ion batteries. Graphite electrodes, which are usually sensitive to the composition of the electrolyte solution, can be successfully cycled at high reversible capacities in several Li salt solutions in this solvent ( , etc.). These results are interesting because lithium ions cannot intercalate into graphite in diethyl carbonate solutions and cycle poorly in dimethyl carbonate solutions. To understand the high compatibility of EMC for Li‐ion battery systems as compared with the other two open‐chain alkyl carbonates mentioned above, the surface chemistry developed in both Li and carbon electrodes in EMC solution was studied and compared with that developed on these electrodes in other alkyl carbonate solutions. Basically, the major surface species formed on both electrodes in EMC include ROLi, , and species. The uniqueness of EMC as a battery solvent is discussed in light of these studies.
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Electrolytes using ethyl methyl carbonate as the single solvent can work on graphite anodes without ethylene carbonate when LiAsF6 salt is used.
“The electrolytes using EMC as the single solvent can even work on graphite anodes without EC when LiAsF 6 salt was used [24].”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [24]
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- Authors
- Ein‐Eli, Y., Thomas, S. R., Koch, V., Aurbach, D., Markovsky, B., & Schechter, A.
- Affiliations
- Bar-Ilan University (IL)
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1996-12-01
- Volume
- 143
- Issue
- 12
- Pages
- L273-L277
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2063401864
- Cited by
- 92
- References
- 0
- Citations by year
- 2025: 1 · 2024: 5 · 2023: 1 · 2022: 1 · 2021: 2 · 2020: 4 · 2019: 5 · 2018: 5 · 2017: 5 · 2016: 2 · 2015: 2 · 2014: 1 · 2013: 2 · 2012: 2
- FWCI
- 6.79
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Journal of The Electrochemical Society (publishedVersion)
- Funders
- Office of Naval Research
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Automotive Engineering › Advanced Battery Technologies Research
- Keywords
- lithium-ion battery electrolytes, graphite electrodes, lithium salt electrolytes, electrode surface chemistry, lithium intercalation, diethyl carbonate, dimethyl carbonate, reversible capacity
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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