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XPS Identification of the Organic and Inorganic Components of the Electrode/Electrolyte Interface Formed on a Metallic Cathode
Open accessAbstract
X-ray photoelectron spectroscopy (XPS) was used to determine the nature and composition of electrode/electrolyte interfaces forming during the cycling of Li-based cells in ethylene carbonate:dimethyl carbonate electrolyte using a heat-treated stainless steel substrate as the positive electrode. From a classical analysis of the XPS C 1s, O 1s, F 1s, P 2p, and Li 1s core peak spectra complemented by an unusual detailed interpretation of XPS valence spectra, we could follow, as a function of the cell cycling history, the evolution and nature of the species constituting the organic/inorganic layer as well as determine its approximate composition. We have shown that this surface layer mainly consists of PEO oligomers , carbonates and/or , salt, and of degradation products of the salt such as LiF and phosphates. Moreover, we give evidence that this layer does not only grow but also becomes richer in and LiF species upon cycling.
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Cites
Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes
Peled, E., Golodnitsky, D., & Ardel, G. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1837858 · Cited by 1,205
Cited by
Cabana, J., Monconduit, L., Larcher, D., & Palacín, M. R. (2010) · Advanced Materials · doi:10.1002/adma.201000717 · Cited by 2,361
Markevich, E., Salitra, G., & Aurbach, D. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00163 · Cited by 502
Direct in situ measurements of Li transport in Li-ion battery negative electrodes
Harris, S. J., Timmons, A., Baker, D. R., & Monroe, C. (2010) · Chemical Physics Letters · doi:10.1016/j.cplett.2009.12.033 · Cited by 434
Deciphering the multi-step degradation mechanisms of carbonate-based electrolyte in Li batteries
Gachot, G., Grugeon, S., Armand, M., Pilard, S., Guenot, P., Tarascon, J.-M., & Laruelle, S. (2008) · Journal of Power Sources · doi:10.1016/j.jpowsour.2007.11.110 · Cited by 425
Self-citationJurng, S., Brown, Z. L., Kim, J., & Lucht, B. L. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00364e · Cited by 417
Metadata
- Authors
- Dedryvère, R., Laruelle, S., Grugeon, S., Gireaud, L., Tarascon, J.-M., & Gonbeau, D.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2005
- Volume
- 152
- Issue
- 4
- Pages
- A689
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W1975046816
- Cited by
- 287
- References
- 1
- FWCI
- 6.36
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Dedryvère, R., Laruelle, S., Grugeon, S., Gireaud, L., Tarascon, J.-M., & Gonbeau, D. (2005). XPS Identification of the Organic and Inorganic Components of the Electrode/Electrolyte Interface Formed on a Metallic Cathode. Journal of The Electrochemical Society. https://doi.org/10.1149/1.1861994
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
