The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Role of Chemical and Structural Stabilities on the Electrochemical Properties of Layered LiNi[sub 1∕3]Mn[sub 1∕3]Co[sub 1∕3]O[sub 2] Cathodes
Abstract
With an aim to develop an understanding of the higher reversible capacities exhibited by the layered LiNi 1 ∕ 3 Mn 1 ∕ 3 Co 1 ∕ 3 O 2 cathode compared to that of LiCoO 2 , its chemical and structural stabilities are investigated by characterizing the samples obtained by chemical lithium extraction. The LiNi 1 ∕ 3 Mn 1 ∕ 3 Co 1 ∕ 3 O 2 cathode prepared by firing the coprecipitated hydroxides of the transition metal ions with 7 atom % excess lithium hydroxide exhibits a discharge capacity of 180 mAh ∕ g (at 4.6 ‐ 3.0 V and C ∕ 5 rate) with 90% capacity retention in 50 cycles. The higher reversible capacity of LiNi 1 ∕ 3 Mn 1 ∕ 3 Co 1 ∕ 3 O 2 is attributed to its better chemical and structural stability down to a lower lithium content of ( 1 − x ) ≈ 0.35 compared to ( 1 − x ) ≈ 0.5 with the analogous Li 1 − x CoO 2 cathode. The Li 1 − x Ni 1 ∕ 3 Mn 1 ∕ 3 Co 1 ∕ 3 O 2 system is found to be chemically stable for ( 1 − x ) 0.35 without tending to lose any oxygen from the lattice and structurally stable for at least ( 1 − x ) 0.23 by maintaining the initial O3 structure.
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Cited by
Ryu, H.-H., Park, K.-J., Yoon, C. S., & Sun, Y.-K. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b05269 · Cited by 1,629
Automotive Li-Ion Batteries: Current Status and Future Perspectives
Ding, Y., Cano, Z. P., Yu, A., Lu, J., & Chen, Z. (2019) · Electrochemical Energy Reviews · doi:10.1007/s41918-018-0022-z · Cited by 1,370
Electrode Degradation in Lithium-Ion Batteries
Pender, J. P., Jha, G., Youn, D. H., Ziegler, J. M., Andoni, I., Choi, E. J., Heller, A., Dunn, B. S., Weiss, P. S., Penner, R. M., et al. (2020) · ACS Nano · doi:10.1021/acsnano.9b04365 · Cited by 873
Recent progress in cathode materials research for advanced lithium ion batteries
Xu, B., Qian, D., Wang, Z., & Meng, Y. S. (2012) · Materials Science and Engineering: R: Reports · doi:10.1016/j.mser.2012.05.003 · Cited by 834
Nonlinear aging characteristics of lithium-ion cells under different operational conditions
Schuster, S. F., Bach, T., Fleder, E., Müller, J., Brand, M., Sextl, G., & Jossen, A. (2015) · Journal of Energy Storage · doi:10.1016/j.est.2015.05.003 · Cited by 451
Metadata
- Authors
- Choi, J., & Manthiram, A.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2005
- Volume
- 152
- Issue
- 9
- Pages
- A1714
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W1574620245
- Cited by
- 291
- References
- 18
- FWCI
- 11.12
- Type
- journal article
- Language
- en
- Open access
- closed
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