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The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries: II . Graphite Electrodes
Open accessAbstract
The electrochemical behavior of Li‐graphite intercalation anodes in ethylene and diethyl carbonates (EC‐DEC) solutions was studied using surface sensitive Fourier transform infrared spectroscopy (FTIR) and impedance spectroscopy in conjunction with standard electrochemical techniques. Three different solvent combinations, four different salts: , , , and , and the influence of the presence of were investigated. Graphite electrodes could be cycled hundreds of times obtaining a reasonable reversible capacity. The best electrolyte was found to be and the presence of in solutions considerably increased the reversible capacity upon cycling. This improved performance is due to precipitation of the ethylene carbonate reduction product, , which is an excellent passivating agent, on the electrode surface. Aging processes of these surface films and their influence on the electrode properties are discussed.
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Cited by
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Identifying the components of the solid–electrolyte interphase in Li-ion batteries
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Metadata
- Authors
- Aurbach, D., Ein‐Eli, Y., Markovsky, B., Zaban, A., Luski, S., Carmeli, Y., & Yamin, H.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1995-09-01
- Volume
- 142
- Issue
- 9
- Pages
- 2882-2890
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W1660831359
- Cited by
- 454
- References
- 0
- FWCI
- 12.93
- Type
- journal article
- Language
- en
- Open access
- bronze
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- CoChat. (2026). Citation check: The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries: II . Graphite Electrodes. https://app.cochat.ai/papers/10.1149/1.2048659
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- Aurbach, D., Ein‐Eli, Y., Markovsky, B., Zaban, A., Luski, S., Carmeli, Y., & Yamin, H. (1995). The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries: II . Graphite Electrodes. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2048659
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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