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Li Metal‐Free Rechargeable Batteries Based on Li1 + x Mn2 O 4 Cathodes ( 0 ≤ x ≤ 1 ) and Carbon Anodes
Open accessAbstract
We show that the spinel , can also be used as the cathode in rechargeable rocking‐chair batteries based on lithium intercalation anodes (carbon, either graphite or petroleum coke). At room temperature, such cells show promising cycle life, an average open‐circuit voltage of 3.7 V and a specific energy of 250 Wh/kg of electrode materials . In addition, we report a novel easily reproducible solution technique for synthesizing , at low temperatures (<100°C), using as a mild reducing agent. The cycling behavior of rocking‐chair cells using this lithiated phase as the starting cathode is presented. appears to be a promising practical "air stable" Li‐bearing cathode for rocking‐chair‐type rechargeable cells.
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Cited by
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A LiMn2O4-Polypyrrole System for the Extraction of LiCl from Natural Brine
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Metadata
- Authors
- Tarascon, J. M., & Guyomard, D.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1991-10-01
- Volume
- 138
- Issue
- 10
- Pages
- 2864-2868
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W1498927032
- Cited by
- 411
- References
- 0
- FWCI
- 13.37
- Type
- journal article
- Language
- en
- Open access
- bronze
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- CoChat. (2026). Citation check: Li Metal‐Free Rechargeable Batteries Based on Li1 + x Mn2 O 4 Cathodes ( 0 ≤ x ≤ 1 ) and Carbon Anodes. https://app.cochat.ai/papers/10.1149/1.2085331
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- Tarascon, J. M., & Guyomard, D. (1991). Li Metal‐Free Rechargeable Batteries Based on Li1 + x Mn2 O 4 Cathodes ( 0 ≤ x ≤ 1 ) and Carbon Anodes. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2085331
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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