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Anodic Iridium Oxide Films: XPS‐Studies of Oxidation State Changes and
Open accessAbstract
The anodic oxidation of iridium and evolution on iridium oxide films in has been investigated using x‐ray photoelectron spectroscopy. The binding energy of the O 1s level decreases with anodic polarization of the electrode while the relative amount of oxygen compared to iridium remains constant. The XPS results are consistent with a model of subsequent deprotonation of the anodic iridium oxide upon anodic polarization. A reaction path for evolution and corrosion on iridium oxide is proposed. Valence band spectra of the oxide surfaces confirm the proposed model.
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Cited by
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
Cherevko, S., Geiger, S., Kasian, O., Kulyk, N., Grote, J.-P., Savan, A., Shrestha, B. R., Merzlikin, S., Breitbach, B., Ludwig, A., et al. (2016) · Catalysis Today · doi:10.1016/j.cattod.2015.08.014 · Cited by 1,448
Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction
Fabbri, E., Habereder, A., Waltar, K., Kötz, R., & Schmidt, T. J. (2014) · Catal. Sci. Technol. · doi:10.1039/c4cy00669k · Cited by 1,303
Self-citationThe stability number as a metric for electrocatalyst stability benchmarking
Geiger, S., Kasian, O., Ledendecker, M., Pizzutilo, E., Mingers, A. M., Fu, W. T., Diaz-Morales, O., Li, Z., Oellers, T., Fruchter, L., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0085-6 · Cited by 1,045
Recent Progress on Multimetal Oxide Catalysts for the Oxygen Evolution Reaction
Kim, J. S., Kim, B., Kim, H., & Kang, K. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702774 · Cited by 940
Metadata
- Authors
- Kötz, R., Neff, H., & Stucki, S.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1984-01-01
- Volume
- 131
- Issue
- 1
- Pages
- 72-77
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W1563260673
- Cited by
- 404
- References
- 0
- FWCI
- 3.68
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Kötz, R., Neff, H., & Stucki, S. (1984). Anodic Iridium Oxide Films: XPS‐Studies of Oxidation State Changes and. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2115548
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