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Efficient p ‐ InP ( Rh ‐ H alloy ) and p ‐ InP ( Re ‐ H alloy ) Hydrogen Evolving Photocathodes
Open accessAbstract
The solar to chemical energy conversion efficiencies of hydrogen generating photoelectrolytic cells with (Rh‐H alloy) and (Re‐H alloy) photocathodes have been increased, respectively, to 16.2% and 14.4%, as calculated from the electrical energy conserved in the photoassisted electrolysis of . Based on the electrical energy produced from the photoelectrochemically generated hydrogen in an ideal fuel cell operating at the thermodynamic potential, the solar to chemical conversion efficiences are, respectively, 13.3% and 11.4%. The cells were improved by increasing the barrier at the junction by hydrogen saturation, while maintaining the recombination passivating layer of hydrated indium oxide at pores in the thin, light transmitting metallic catalyst layer.
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Cited by
Walter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010) · Chemical Reviews · doi:10.1021/cr1002326 · Cited by 9,388
Abe, R. (2010) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2011.02.003 · Cited by 1,223
Earth-abundant hydrogen evolution electrocatalysts
McKone, J. R., Marinescu, S. C., Brunschwig, B. S., Winkler, J. R., & Gray, H. B. (2014) · Chem. Sci. · doi:10.1039/c3sc51711j · Cited by 727
Man, H.-W., Tsang, C.-S., Li, M. M.-J., Mo, J., Huang, B., Lee, L. Y. S., Leung, Y.-C., Wong, K.-Y., & Tsang, S. C. E. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.09.103 · Cited by 169
Metadata
- Authors
- Aharon‐Shalom, E., & Heller, A.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1982-12-01
- Volume
- 129
- Issue
- 12
- Pages
- 2865-2866
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2010143785
- Cited by
- 171
- References
- 0
- FWCI
- 10.68
- Type
- journal article
- Language
- en
- Open access
- bronze
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- CoChat. (2026). Citation check: Efficient p ‐ InP ( Rh ‐ H alloy ) and p ‐ InP ( Re ‐ H alloy ) Hydrogen Evolving Photocathodes. https://app.cochat.ai/papers/10.1149/1.2123695
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- Aharon‐Shalom, E., & Heller, A. (1982). Efficient p ‐ InP ( Rh ‐ H alloy ) and p ‐ InP ( Re ‐ H alloy ) Hydrogen Evolving Photocathodes. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2123695
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