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Electrochemistry of Prussian Blue Modified Electrodes: An Electrochemical Preparation Method
Abstract
A new type of Prussian blue modified electrode is described. The Prussian blue modified electrode is electrochemically prepared in a solution of ferric‐ferricyanide. The amount of Prussian blue on electrodes such as platinum, glassy carbon, and SnO 2 is easily controlled by changing the current density, the electrode potential, and the time of the electrolysis. The waves observed at +0.2 and +1.0V vs. SCE are due to the reduction and the oxidation of the ferric part and of the ferrous part in the Prussian blue crystal, KFe III Fe II ( CN ) 6 or Fe 4 III [ Fe II ( CN ) 6 ] 3 , respectively. This electrode exhibits excellent stability in aqueous solution. A spectroelectrochemical property of the modified electrode is also described.
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Citations
Cited by
Sensor and biosensor preparation, optimisation and applications of Prussian Blue modified electrodes
Ricci, F., & Palleschi, G. (2005) · Biosensors and Bioelectronics · doi:10.1016/j.bios.2004.12.001 · Cited by 781
Wang, J., Zhang, L., Yu, L., Jiao, Z., Xie, H., Lou, X. W., & Wei Sun, X. (2014) · Nature Communications · doi:10.1038/ncomms5921 · Cited by 465
Ricci, F., Amine, A., Palleschi, G., & Moscone, D. (2003) · Biosensors and Bioelectronics · doi:10.1016/s0956-5663(02)00169-0 · Cited by 349
A Review on Recent Advances in Electrochromic Devices: A Material Approach
Rai, V., Singh, R. S., Blackwood, D. J., & Zhili, D. (2020) · Advanced Engineering Materials · doi:10.1002/adem.202000082 · Cited by 285
Metadata
- Authors
- Itaya, K., Akahoshi, H., & Toshima, S.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1982-07-01
- Volume
- 129
- Issue
- 7
- Pages
- 1498-1500
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2065947912
- Cited by
- 271
- References
- 0
- FWCI
- 4.74
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Electrochemistry of Prussian Blue Modified Electrodes: An Electrochemical Preparation Method. https://app.cochat.ai/papers/10.1149/1.2124191
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- Itaya, K., Akahoshi, H., & Toshima, S. (1982). Electrochemistry of Prussian Blue Modified Electrodes: An Electrochemical Preparation Method. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2124191
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