The DOI matches its Crossref record.
The Role of Ternary Phases in Cathode Reactions
Open accessAbstract
The cell reactions between lithium and several transition metal oxides and sulfides have been found to produce ternary phases and not the formation of lithium oxide or sulfide as previously proposed. These reactions, at 25°C, take place with essential retention of the crystalline lattice, thus facilitating secondary cathodic behavior. It is found that cell reversibility is optimized when no chemical bonds are broken during discharge, that is, where ternary phases are formed by an intercalation reaction and where a broad range of nonstoichiometry exists as in the system . Where some chemical bonds are broken as for and partial or difficult reversibility is found, but when all the bonds are broken as for example in , the cell only exhibits primary characteristics.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Electrical Energy Storage and Intercalation Chemistry
Whittingham, M. S. (1976) · Science · doi:10.1126/science.192.4244.1126 · Cited by 1,919
Self-citationLayered vanadium and molybdenum oxides: batteries and electrochromics
Chernova, N. A., Roppolo, M., Dillon, A. C., & Whittingham, M. S. (2009) · Journal of Materials Chemistry · doi:10.1039/b819629j · Cited by 874
Self-citationHistory, Evolution, and Future Status of Energy Storage
Whittingham, M. S. (2012) · Proceedings of the IEEE · doi:10.1109/jproc.2012.2190170 · Cited by 873
Self-citationNanostructured Mo-based electrode materials for electrochemical energy storage
Hu, X., Zhang, W., Liu, X., Mei, Y., & Huang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00350k · Cited by 711
Vanadium‐Based Nanomaterials: A Promising Family for Emerging Metal‐Ion Batteries
Xu, X., Xiong, F., Meng, J., Wang, X., Niu, C., An, Q., & Mai, L. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201904398 · Cited by 482
Metadata
- Authors
- Whittingham, M. S.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 1976-03-01
- Volume
- 123
- Issue
- 3
- Pages
- 315-320
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W1983463901
- Cited by
- 726
- References
- 0
- FWCI
- 36.14
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: The Role of Ternary Phases in Cathode Reactions. https://app.cochat.ai/papers/10.1149/1.2132817
- The paper
- Whittingham, M. S. (1976). The Role of Ternary Phases in Cathode Reactions. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2132817
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
