The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Hydrogen Peroxide Formation Rates in a PEMFC Anode and Cathode
Open accessAbstract
Hydrogen peroxide formation rates in a proton exchange membrane fuel cell (PEMFC) anode and cathode were estimated as a function of humidity and temperature by studying the oxygen reduction reaction (ORR) on a rotating ring disk electrode. Fuel cell conditions were replicated by depositing a film of Pt/Vulcan XC-72 catalyst onto the disk and by varying the temperature, dissolved concentration, and the acidity levels in hydrochloric acid . The acidity was correlated to ionomer water activity and hence fuel cell humidity. The formation rates showed a linear dependence on oxygen concentration and square dependence on water activity. The selectivity in ORR was independent of oxygen concentration but increased with the decrease in water activity (i.e., decreased humidity). Potential dependent activation energy for the formation reaction was estimated from data obtained at different temperatures.
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Cites
Characterization of High‐Surface‐Area Electrocatalysts Using a Rotating Disk Electrode Configuration
Schmidt, T. J., Gasteiger, H. A., Stäb, G. D., Urban, P. M., Kolb, D. M., & Behm, R. J. (1998) · Journal of The Electrochemical Society · doi:10.1149/1.1838642 · Cited by 1,131
Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranes
Zawodzinski, T. A., Neeman, M., Sillerud, L. O., & Gottesfeld, S. (1991) · The Journal of Physical Chemistry · doi:10.1021/j100168a060 · Cited by 987
Advanced materials for improved PEMFC performance and life
Curtin, D. E., Lousenberg, R. D., Henry, T. J., Tangeman, P. C., & Tisack, M. E. (2004) · Journal of Power Sources · doi:10.1016/j.jpowsour.2004.01.023 · Cited by 786
Paulus, U. A., Wokaun, A., Scherer, G. G., Schmidt, T. J., Stamenkovic, V., Markovic, N. M., & Ross, P. N. (2002) · Electrochimica Acta · doi:10.1016/s0013-4686(02)00349-3 · Cited by 560
Water Uptake of Perfluorosulfonic Acid Membranes from Liquid Water and Water Vapor
Hinatsu, J. T., Mizuhata, M., & Takenaka, H. (1994) · Journal of The Electrochemical Society · doi:10.1149/1.2054951 · Cited by 518
Diffusion of Water in Nafion 115 Membranes
Motupally, S., Becker, A. J., & Weidner, J. W. (2000) · Journal of The Electrochemical Society · doi:10.1149/1.1393879 · Cited by 478
Self-citationKinetics of O 2 Reduction on a Pt Electrode Covered with a Thin Film of Solid Polymer Electrolyte
Zecevic, S. K., Wainright, J. S., Litt, M. H., Gojkovic, S. L., & Savinell, R. F. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1837946 · Cited by 209
Cited by
Zatoń, M., Rozière, J., & Jones, D. J. (2017) · Sustainable Energy & Fuels · doi:10.1039/c7se00038c · Cited by 435
Pressurized PEM water electrolysis: Efficiency and gas crossover
Schalenbach, M., Carmo, M., Fritz, D. L., Mergel, J., & Stolten, D. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.09.013 · Cited by 400
Review: Direct and Indirect Electrical Stimulation of Microbial Metabolism
Thrash, J. C., & Coates, J. D. (2008) · Environmental Science & Technology · doi:10.1021/es702668w · Cited by 375
Du, L., Prabhakaran, V., Xie, X., Park, S., Wang, Y., & Shao, Y. (2021) · Advanced Materials · doi:10.1002/adma.201908232 · Cited by 357
Membrane degradation in PEM fuel cells: From experimental results to semi-empirical degradation laws
Chandesris, M., Vincent, R., Guetaz, L., Roch, J.-S., Thoby, D., & Quinaud, M. (2017) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2017.02.116 · Cited by 186
Metadata
- Authors
- Sethuraman, V. A., Weidner, J. W., Haug, A. T., Motupally, S., & Protsailo, L. V.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2008
- Volume
- 155
- Issue
- 1
- Pages
- B50
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W4288083648
- Cited by
- 201
- References
- 7
- FWCI
- 4.53
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Sethuraman, V. A., Weidner, J. W., Haug, A. T., Motupally, S., & Protsailo, L. V. (2008). Hydrogen Peroxide Formation Rates in a PEMFC Anode and Cathode. Journal of The Electrochemical Society. https://doi.org/10.1149/1.2801980
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.