Oxygen Reduction Reaction on Platinum/Tantalum Oxide Electrocatalysts for PEM Fuel Cells
Abstract
Oxygen Reduction Reaction on Platinum/Tantalum Oxide Electrocatalysts for PEM Fuel Cells, Baturina, Olga A., Garsany, Yannick, Zega, Thomas J., Stroud, Rhonda M., Schull, Terence, Swider-Lyons, Karen E.
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The higher area-specific activity of Pt/Ta2O5/VC may be due to preferential adsorption of OH groups to the oxide versus the platinum surface.
“The higher area-specic activity of the catalyst may be due to the preferential adsorption of OH groups to the oxide vs. platinum surface.112”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [112]
The area-specific activity of Pt/Ta2O5/VC for the ORR at 0.9 V was 1.5-2 times higher than that of standard Pt/VC.
“It was found that the area-specic activity of Pt/Ta 2 O 5 /VC for the ORR at 0.9 V was 1.5-2 times higher than that of standard Pt/VC.”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [112]
According to the d-band approach explored with density functional theory, tantalum(V) should bring down the d-band centre of platinum, which would result in weaker bonding between platinum and adsorbed oxygen species.
“According to the d-band approach explored with density functional theory, tantalum(V) should bring down the d-band centre of platinum, which would result in a weaker bonding between platinum and adsorbed oxygen species.”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [112]
Strong metal support interaction modifies the Fermi level of Pt and creates an excess of OH groups that cause quick dissociation of O−H bonds on the catalyst interface.
“(d) strong metal support interaction modifies the Fermi level of Pt and creates an excess of OH groups that cause quick dissociation of O−H bonds on the catalyst interface.”
From Highly Dispersed Pt Clusters on F-Doped Tin(IV) Oxide Aerogel Matrix: An Ultra-Robust Hybrid Catalyst for Enhanced Hydrogen Evolution (2022) · cites this paper as [31]
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- Authors
- Baturina, O. A., Garsany, Y., Zega, T. J., Stroud, R. M., Schull, T., & Swider-Lyons, K. E.
- Affiliations
- United States Naval Research Laboratory (US)
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2008
- Volume
- 155
- Issue
- 12
- Pages
- B1314
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2139401481
- Cited by
- 60
- References
- 26
- Citations by year
- 2026: 1 · 2025: 3 · 2024: 3 · 2023: 5 · 2022: 1 · 2021: 2 · 2020: 4 · 2019: 2 · 2018: 2 · 2017: 3 · 2016: 5 · 2015: 3 · 2014: 5 · 2013: 5 · 2012: 7
- FWCI
- 1.71
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of The Electrochemical Society (publishedVersion)
- Funders
- Office of Naval Research
- U.S. Naval Research Laboratory
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Keywords
- oxygen reduction reaction, proton exchange membrane fuel cells, electrocatalysts, platinum catalysts, tantalum oxide
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