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Bimetallic Ru Electrocatalysts for the OER and Electrolytic Water Splitting in Acidic Media
Abstract
We have explored bimetallic Ru–M oxygen evolution reaction (OER) electrocatalysts for use in water splitting in acidic electrolytes. Using an electrochemical multielectrode cell, we investigated the OER activity of selected compositions of seven binary alloy systems, Ru–M ( M = Pd , Ir , Cu , Co , Re , Cr , Ni ) . Benchmarked using pure Ru electrocatalysts, Ru–Co, Ru–Ir, and Ru–Cu exhibited improved Ru mass-based catalytic activities. Structural studies of the precursor alloys indicated the presence of hexagonal and cubic mixed metal phases. We hypothesize that the secondary metal component modulates the chemisorption energy of oxygen, which was suggested to be a sensitive rate controlling parameter in the OER catalysis and favors the formation of atomic oxygen O ad and possibly HOO ad species rather than OH ad species on the oxide catalyst.
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Cited by
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Self-citationAnantharaj, S., Ede, S. R., Karthick, K., Sam Sankar, S., Sangeetha, K., Karthik, P. E., & Kundu, S. (2018) · Energy & Environmental Science · doi:10.1039/c7ee03457a · Cited by 1,632
Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction
Fabbri, E., Habereder, A., Waltar, K., Kötz, R., & Schmidt, T. J. (2014) · Catal. Sci. Technol. · doi:10.1039/c4cy00669k · Cited by 1,303
Reier, T., Nong, H. N., Teschner, D., Schlögl, R., & Strasser, P. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601275 · Cited by 1,253
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Metadata
- Authors
- Forgie, R., Bugosh, G., Neyerlin, K. C., Liu, Z., & Strasser, P.
- Venue
- Electrochemical and Solid-State Letters
- Publisher
- The Electrochemical Society
- Published
- 2010
- Volume
- 13
- Issue
- 4
- Pages
- B36
- ISSN
- 1099-0062 (ISSN-L)
- OpenAlex
- W2137325882
- Cited by
- 174
- References
- 0
- FWCI
- 4.60
- Type
- journal article
- Language
- en
- Open access
- closed
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- Forgie, R., Bugosh, G., Neyerlin, K. C., Liu, Z., & Strasser, P. (2010). Bimetallic Ru Electrocatalysts for the OER and Electrolytic Water Splitting in Acidic Media. Electrochemical and Solid-State Letters. https://doi.org/10.1149/1.3290735
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