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Bimetallic Ru Electrocatalysts for the OER and Electrolytic Water Splitting in Acidic Media

Forgie, Rhys, Bugosh, Greg, Neyerlin, K. C., Liu, Zengcai, Strasser, Peter·2010·Electrochemical and Solid-State Letters

Abstract

We have explored bimetallic Ru–M oxygen evolution reaction (OER) electrocatalysts for use in water splitting in acidic electrolytes. Using an electrochemical multielectrode cell, we investigated the OER activity of selected compositions of seven binary alloy systems, Ru–M ( M = Pd , Ir , Cu , Co , Re , Cr , Ni ) . Benchmarked using pure Ru electrocatalysts, Ru–Co, Ru–Ir, and Ru–Cu exhibited improved Ru mass-based catalytic activities. Structural studies of the precursor alloys indicated the presence of hexagonal and cubic mixed metal phases. We hypothesize that the secondary metal component modulates the chemisorption energy of oxygen, which was suggested to be a sensitive rate controlling parameter in the OER catalysis and favors the formation of atomic oxygen O ad and possibly HOO ad species rather than OH ad species on the oxide catalyst.

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Metadata

Authors
Forgie, R., Bugosh, G., Neyerlin, K. C., Liu, Z., & Strasser, P.
Venue
Electrochemical and Solid-State Letters
Published
2010
Volume
13
Issue
4
Pages
B36
ISSN
1099-0062 (ISSN-L)
OpenAlex
W2137325882
Cited by
174
References
0
FWCI
4.60
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Bimetallic Ru Electrocatalysts for the OER and Electrolytic Water Splitting in Acidic Media. https://app.cochat.ai/papers/10.1149/1.3290735
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Forgie, R., Bugosh, G., Neyerlin, K. C., Liu, Z., & Strasser, P. (2010). Bimetallic Ru Electrocatalysts for the OER and Electrolytic Water Splitting in Acidic Media. Electrochemical and Solid-State Letters. https://doi.org/10.1149/1.3290735

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