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Cited by 34Electrocatalysts for Energy ConversionFuel Cells and Related MaterialsCatalytic Processes in Materials Science

Synthesis and Properties of Platinum Nanocatalyst Supported on Cellulose-Based Carbon Aerogel for Applications in PEMFCs

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Rooke, Joanna, de Matos Passos, Camila, Chatenet, Marian, Sescousse, Romain, Budtova, Tatiana, Berthon-Fabry, Sandrine, Mosdale, Renaut, Maillard, Frédéric·2011·Journal of The Electrochemical Society
DOI 10.1149/1.3585744
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Abstract

Platinum nanoparticles supported on nanostructured cellulose-based carbon aerogels (carbonized aerocellulose, CAC) were evaluated in proton exchange membrane fuel cell (PEMFC). The CAC substrate was synthesized through the dissolution, gelation, regeneration, supercritical CO 2 drying and pyrolysis of cellulose. The Pt nanoparticles deposition was performed by impregnation of the CAC with H 2 PtCl 6 , followed by Pt z+ species reduction either under H 2 at 300–400°C or in basic NaBH 4 solution. While H 2 reduction leads to uniform Pt nanoparticles well-dispersed over the CAC surface, larger agglomerates form with NaBH 4 reduction, as revealed by transmission electron microscopy (TEM) and powder X-ray diffraction (XRD). The reduction methods influences the quantity of platinum deposited, which may be increased by using multiple impregnation/reduction steps. The specific surface area of Pt and specific/mass activities towards oxygen reduction of the Pt/CAC materials, investigated using the rotating disk electrode setup, are similar to those of commercial Pt/Carbon Black (CB). Finally, PEMFC unit cell testing demonstrates that a Pt/CAC sample synthesized using three successive impregnation/reduction steps, loaded at ca . 14 wt % Pt/(Pt + C), competes with state-of-the-art Pt/CB electrocatalysts of comparable Pt loading.

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Cited by

Sorted by citations

Authors
Rooke, J., de Matos Passos, C., Chatenet, M., Sescousse, R., Budtova, T., Berthon-Fabry, S., Mosdale, R., & Maillard, F.
Affiliations
  • Institut polytechnique de Grenoble (FR)
  • Centre de Mise en Forme des Matériaux (FR)
  • PaxiTech (France) (FR)
ORCID
Venue
Journal of The Electrochemical Society
Publisher
The Electrochemical Society
Published
2011
Volume
158
Issue
7
Pages
B779
ISSN
0013-4651 (ISSN-L)
DOI
10.1149/1.3585744
OpenAlex
W2088326885
Cited by
34
References
0
Citations by year
2025: 1 · 2023: 3 · 2021: 2 · 2020: 3 · 2019: 2 · 2018: 1 · 2017: 2 · 2016: 3 · 2015: 4 · 2014: 6 · 2013: 3 · 2012: 3
FWCI
1.73
Type
journal article
Language
en
Open access
Locations
  • Journal of The Electrochemical Society (publishedVersion)
  • HAL (submittedVersion)
Funders
Agence Nationale de la Recherche (ANR-06-MAPR-0004)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
  • Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
Keywords
platinum nanoparticles, carbon aerogels, proton exchange membrane fuel cells, oxygen reduction reaction, electrocatalysts, supercritical CO2 drying, pyrolysis, impregnation-reduction, sodium borohydride reduction, hydrogen reduction, nanoparticle agglomeration, platinum loading

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