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A Non-Aqueous Asymmetric Cell with a Ti2C-Based Two-Dimensional Negative Electrode
Open accessAbstract
A new MXene phase, Ti 2 C, obtained by aluminum extraction from Ti 2 AlC and exfoliation of the reaction product, was electrochemically studied vs. Lithium. Li-ions insertion into the 2-D structure was characterized by in situ XRD measurements. Additional electrochemical kinetic characterizations of Ti 2 C, using a cavity micro-electrode, showed that the electrochemical reactions involve two different phenomena: one diffusion-limited, the other not. A Ti 2 C/activated carbon asymmetric cell was assembled to highlight the high rate performance of the MXene . The cell was cycled between 1.0 V and 3.5 V, and showed good capacity retention during 1000 galvanostatic charge/discharge cycles at rates up to 10C.
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Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Cited by
Xie, Y., Naguib, M., Mochalin, V. N., Barsoum, M. W., Gogotsi, Y., Yu, X., Nam, K.-W., Yang, X.-Q., Kolesnikov, A. I., & Kent, P. R. C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501520b · Cited by 1,537
Self-citationLarge-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes”
Naguib, M., Unocic, R. R., Armstrong, B. L., & Nanda, J. (2015) · Dalton Transactions · doi:10.1039/c5dt01247c · Cited by 964
Self-citationTwo-Dimensional Ti3C2Tx MXene Nanosheets for Efficient Copper Removal from Water
Shahzad, A., Rasool, K., Miran, W., Nawaz, M., Jang, J., Mahmoud, K. A., & Lee, D. S. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b02695 · Cited by 478
Rational Design of Nanostructured Electrode Materials toward Multifunctional Supercapacitors
Yan, J., Li, S., Lan, B., Wu, Y., & Lee, P. S. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201902564 · Cited by 426
Synthesis and Electrochemical Properties of Two-Dimensional RGO/Ti3C2Tx Nanocomposites
Shen, C., Wang, L., Zhou, A., Wang, B., Wang, X., Lian, W., Hu, Q., Qin, G., & Liu, X. (2018) · Nanomaterials · doi:10.3390/nano8020080 · Cited by 152
Metadata
- Authors
- Come, J., Naguib, M., Rozier, P., Barsoum, M. W., Gogotsi, Y., Taberna, P.-L., Morcrette, M., & Simon, P.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2012
- Volume
- 159
- Issue
- 8
- Pages
- A1368-A1373
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W1964622090
- Cited by
- 395
- References
- 1
- FWCI
- 8.11
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Come, J., Naguib, M., Rozier, P., Barsoum, M. W., Gogotsi, Y., Taberna, P.-L., Morcrette, M., & Simon, P. (2012). A Non-Aqueous Asymmetric Cell with a Ti2C-Based Two-Dimensional Negative Electrode. Journal of The Electrochemical Society. https://doi.org/10.1149/2.003208jes
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