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Cited by 335

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Reduction Reactions of Electrolyte Salts for Lithium Ion Batteries: LiPF6, LiBF4, LiDFOB, LiBOB, and LiTFSI

Open access
Parimalam, Bharathy S., Lucht, Brett L.·2018·Journal of The Electrochemical Society

Abstract

The reduction products of common lithium salts for lithium ion battery electrolytes, LiPF 6 , LiBF 4 , lithium bisoxalato borate (LiBOB), lithium difluorooxalato borate (LiDFOB), and lithium trifluorosulfonylimide (LiTFSI), have been investigated. The solution phase reduction of different lithium salts via reaction with the one electron reducing agent, lithium naphthalenide, results in near quantitative reactions. Analysis of the solution phase and head space gasses suggests that all of the reduction products are precipitated as insoluble solids. The solids obtained through reduction were analyzed with solution NMR, IR-ATR and XPS. All fluorine containing salts generate LiF upon reduction while all oxalate containing salts generate lithium oxalate. In addition, depending upon the salt other species including, Li x PF y O z , Li x BF y , oligomeric borates, and lithium bis[N-(trifluoromethylsulfonylimino)] trifluoromethanesulfonate are observed.

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Metadata

Authors
Parimalam, B. S., & Lucht, B. L.
Venue
Journal of The Electrochemical Society
Published
2018
Volume
165
Issue
2
Pages
A251-A255
ISSN
  • 0013-4651 (ISSN-L)
  • 1945-7111
OpenAlex
W2789452614
Cited by
335
References
1
FWCI
8.28
Type
journal article
Language
en
Open access
hybrid

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