The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.
A Localized High-Concentration Electrolyte with Optimized Solvents and Lithium Difluoro(oxalate)borate Additive for Stable Lithium Metal Batteries
Abstract
We report a carbonate-based localized high-concentration electrolyte (LHCE) with a fluorinated ether as a diluent for 4-V class lithium metal batteries (LMBs), which enables dendrite-free Li deposition with a high Li Coulombic efficiency (∼98.5%) and much better cycling stability for Li metal anodes than previously reported dimethyl carbonate-based LHCEs at lean electrolyte conditions. This electrolyte consists of 1.2 M lithium bis(fluorosulfonyl)imide (LiFSI) in a cosolvent mixture of ethylene carbonate (EC)/ethyl methyl carbonate (EMC) with bis(2,2,2-trifluoroethyl) ether (BTFE) as the diluent and 0.15 M lithium difluoro(oxalate)borate (LiDFOB) as an additive. A Li||LiNi 1/3 Mn 1/3 Co 1/3 O 2 battery with a high areal loading of 3.8 mAh cm –2 maintains 84% of its initial capacity after 100 cycles. The enhanced stability can be attributed to the robust solid–electrolyte interface (SEI) layer formed on the Li metal anode, arising from the preferential decomposition of LiDFOB salt and EC solvent molecules.
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Cites
Rechargeable Lithium–Sulfur Batteries
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High rate and stable cycling of lithium metal anode
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Self-citationFluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries
Zhang, X., Cheng, X., Chen, X., Yan, C., & Zhang, Q. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201605989 · Cited by 1,699
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
Zheng, J., Engelhard, M. H., Mei, D., Jiao, S., Polzin, B. J., Zhang, J.-G., & Xu, W. (2017) · Nature Energy · doi:10.1038/nenergy.2017.12 · Cited by 1,343
Self-citationSuperconcentrated electrolytes for a high-voltage lithium-ion battery
Wang, J., Yamada, Y., Sodeyama, K., Chiang, C. H., Tateyama, Y., & Yamada, A. (2016) · Nature Communications · doi:10.1038/ncomms12032 · Cited by 1,059
Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries
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Lithium–oxygen batteries: bridging mechanistic understanding and battery performance
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Chemical Dealloying Derived 3D Porous Current Collector for Li Metal Anodes
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Electrochemical in situ investigations of SEI and dendrite formation on the lithium metal anode
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Cited by
Pathways for practical high-energy long-cycling lithium metal batteries
Liu, J., Bao, Z., Cui, Y., Dufek, E. J., Goodenough, J. B., Khalifah, P., Li, Q., Liaw, B. Y., Liu, P., Manthiram, A., et al. (2019) · Nature Energy · doi:10.1038/s41560-019-0338-x · Cited by 3,412
Self-citationDesigning Advanced Lithium‐Based Batteries for Low‐Temperature Conditions
Gupta, A., & Manthiram, A. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001972 · Cited by 462
Critical effects of electrolyte recipes for Li and Na metal batteries
Zheng, X., Huang, L., Ye, X., Zhang, J., Min, F., Luo, W., & Huang, Y. (2021) · Chem · doi:10.1016/j.chempr.2021.02.025 · Cited by 367
Self-citationCao, Z., Zheng, X., Qu, Q., Huang, Y., & Zheng, H. (2021) · Advanced Materials · doi:10.1002/adma.202103178 · Cited by 336
Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range
Zhang, X., Zou, L., Xu, Y., Cao, X., Engelhard, M. H., Matthews, B. E., Zhong, L., Wu, H., Jia, H., Ren, X., et al. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202000368 · Cited by 282
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Metadata
- Authors
- Yu, L., Chen, S., Lee, H., Zhang, L., Engelhard, M. H., Li, Q., Jiao, S., Liu, J., Xu, W., & Zhang, J.-G.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-07-31
- Volume
- 3
- Issue
- 9
- Pages
- 2059-2067
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2886895821
- Cited by
- 363
- References
- 24
- FWCI
- 13.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yu, L., Chen, S., Lee, H., Zhang, L., Engelhard, M. H., Li, Q., Jiao, S., Liu, J., Xu, W., & Zhang, J.-G. (2018). A Localized High-Concentration Electrolyte with Optimized Solvents and Lithium Difluoro(oxalate)borate Additive for Stable Lithium Metal Batteries. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.8b00935
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