Na3V2(PO4)3/C Composite Prepared by Sol-Gel Method as Cathode for Sodium Ion Batteries
Abstract
Na 3 V 2 (PO 4 ) 3 (NVP) composites were prepared by a facile sol-gel method. The optimal synthetic conditions were systematically investigated by orthogonal test method and single factor of calcination temperature, which had maximum effect on the electrochemical properties of the sample. The optimal Na 3 V 2 (PO 4 ) 3 /C (denoted as Opt-NVP/C) has been prepared under the condition of the calcination temperature at 800°C, the molar ratio of NVP to C as 1:1, sol-gel reaction temperature at 80°C and the calcination time of 16 h. The capacity retention decreased by only 2% from the initial value of 106.7 mAh g −1 to 104.5 mAh g −1 after 100 cycles at 0.2C. Enhanced electrochemical performance can be attributed to reduced polarization and stable operating voltage window. The high purity and crystallinity at the proper calcination temperature and porous particles morphologies are related to lower polarization and higher Na + diffusion coefficient, respectively.
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The peaks of NVP powder coincide well with the reference PDF card No00-062-0345 of NVP, indicating the absence of any impurities.
“The peaks of NVP powder coincide well with the reference PDF card №00-062-0345 of NVP, indicating the absence of any impurities25”
From High-performance Na3V2(PO4)3/C cathode for efficient low-temperature lithium-ion batteries (2025) · cites this paper as [25]
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High-performance Na3V2(PO4)3/C cathode for efficient low-temperature lithium-ion batteries
Mukushev, I., Tyan, Y., Kalimuldina, G., Mukanova, A., Jakupova, Z., Kim, S.-S., Bakenov, Z., & Nurpeissova, A. (2025) · NPG Asia Materials · doi:10.1038/s41427-025-00591-x · Cited by 11 · see citing works
- Authors
- Luo, S.-H., Li, J.-Y., Bao, S., Liu, Y.-Y., & Wang, Z.
- Affiliations
- Northeastern University (CN)
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2018
- Volume
- 165
- Issue
- 7
- Pages
- A1460-A1465
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2800342550
- Cited by
- 37
- References
- 0
- Citations by year
- 2026: 1 · 2025: 2 · 2024: 9 · 2023: 5 · 2022: 5 · 2021: 5 · 2020: 6 · 2019: 3 · 2018: 1
- FWCI
- 1.44
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of The Electrochemical Society (publishedVersion)
- Funders
- National Natural Science Foundation of China (NSFC) (51674068, 51774002)
- National Natural Science Foundation of Hebei Province (E2018501091)
- Science and Technology Project of Hebei Province (15271302D)
- Training Foundation for Scientufic Research of Talents Project, Hebei Province (A2016005004)
- The Fundamental Research Funds for the Central Universities (N172302001)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Materials Science › Materials Chemistry › Thermal Expansion and Ionic Conductivity
- Keywords
- Na3V2(PO4)3, sodium vanadium phosphate, carbon composite, cathode materials, sodium-ion batteries, sol-gel synthesis, calcination temperature, electrochemical performance, capacity retention, polarization, Na+ diffusion coefficient, porous particles
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