Cited by 37Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic Conductivity

Na3V2(PO4)3/C Composite Prepared by Sol-Gel Method as Cathode for Sodium Ion Batteries

Luo, Shao-hua, Li, Jia-yu, Bao, Shuo, Liu, Ying-ying, Wang, Zhiyuan·2018·Journal of The Electrochemical Society

Abstract

Na 3 V 2 (PO 4 ) 3 (NVP) composites were prepared by a facile sol-gel method. The optimal synthetic conditions were systematically investigated by orthogonal test method and single factor of calcination temperature, which had maximum effect on the electrochemical properties of the sample. The optimal Na 3 V 2 (PO 4 ) 3 /C (denoted as Opt-NVP/C) has been prepared under the condition of the calcination temperature at 800°C, the molar ratio of NVP to C as 1:1, sol-gel reaction temperature at 80°C and the calcination time of 16 h. The capacity retention decreased by only 2% from the initial value of 106.7 mAh g −1 to 104.5 mAh g −1 after 100 cycles at 0.2C. Enhanced electrochemical performance can be attributed to reduced polarization and stable operating voltage window. The high purity and crystallinity at the proper calcination temperature and porous particles morphologies are related to lower polarization and higher Na + diffusion coefficient, respectively.

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Crossref · 10.1149/2.0961807jes

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Authors
Luo, S.-H., Li, J.-Y., Bao, S., Liu, Y.-Y., & Wang, Z.
Affiliations
Northeastern University (CN)
Venue
Journal of The Electrochemical Society
Published
2018
Volume
165
Issue
7
Pages
A1460-A1465
ISSN
  • 0013-4651 (ISSN-L)
  • 1945-7111
OpenAlex
W2800342550
Cited by
37
References
0
Citations by year
2026: 1 · 2025: 2 · 2024: 9 · 2023: 5 · 2022: 5 · 2021: 5 · 2020: 6 · 2019: 3 · 2018: 1
FWCI
1.44
Type
journal article
Language
en
Open access
closed
Locations
Journal of The Electrochemical Society (publishedVersion)
Funders
  • National Natural Science Foundation of China (NSFC) (51674068, 51774002)
  • National Natural Science Foundation of Hebei Province (E2018501091)
  • Science and Technology Project of Hebei Province (15271302D)
  • Training Foundation for Scientufic Research of Talents Project, Hebei Province (A2016005004)
  • The Fundamental Research Funds for the Central Universities (N172302001)
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
  • Physical Sciences › Materials Science › Materials Chemistry › Thermal Expansion and Ionic Conductivity
Keywords
Na3V2(PO4)3, sodium vanadium phosphate, carbon composite, cathode materials, sodium-ion batteries, sol-gel synthesis, calcination temperature, electrochemical performance, capacity retention, polarization, Na+ diffusion coefficient, porous particles

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