Cited by 238Battery Modeling and ManagementAdvancements in Battery MaterialsExtraction and Separation Processes

The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.

Comprehensive Modeling of Temperature-Dependent Degradation Mechanisms in Lithium Iron Phosphate Batteries

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Schimpe, M., von Kuepach, M. E., Naumann, M., Hesse, H. C., Smith, K., Jossen, A.·2018·Journal of The Electrochemical Society

Abstract

For reliable lifetime predictions of lithium-ion batteries, models for cell degradation are required. A comprehensive semi-empirical model based on a reduced set of internal cell parameters and physically justified degradation functions for the capacity loss is developed and presented for a commercial lithium iron phosphate/graphite cell. One calendar and several cycle aging effects are modeled separately. Emphasis is placed on the varying degradation at different temperatures. Degradation mechanisms for cycle aging at high and low temperatures as well as the increased cycling degradation at high state of charge are calculated separately. For parameterization, a lifetime test study is conducted including storage and cycle tests. Additionally, the model is validated through a dynamic current profile based on real-world application in a stationary energy storage system revealing the accuracy. Tests for validation are continued for up to 114 days after the longest parametrization tests. The model error for the cell capacity loss in the application-based tests is at the end of testing below 1% of the original cell capacity and the maximum relative model error is below 21%.

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  1. Yasuda Masayuki , in OREBA 1.0 - International Conference on Olivines for Rechargeable Batteries, (2014).

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Metadata

Authors
Schimpe, M., von Kuepach, M. E., Naumann, M., Hesse, H. C., Smith, K., & Jossen, A.
Affiliations
  • Technical University of Munich (DE)
  • National Laboratory of the Rockies (US)
Venue
Journal of The Electrochemical Society
Published
2018
Volume
165
Issue
2
Pages
A181-A193
ISSN
  • 0013-4651 (ISSN-L)
  • 1945-7111
OpenAlex
W2782996909
Cited by
238
References
26
Citations by year
2026: 40 · 2025: 30 · 2024: 38 · 2023: 28 · 2022: 34 · 2021: 37 · 2020: 17 · 2019: 9 · 2018: 5
FWCI
9.04
Type
journal article
Language
en
Open access
Licence
cc-by
Locations
  • Journal of The Electrochemical Society (publishedVersion, cc-by)
  • OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
  • mediaTUM – the media and publications repository of the Technical University Munich (Technical University Munich) (submittedVersion, other-oa)
Funders
  • Bundesministerium für Wirtschaft und Energie (Federal Ministry for Economic Affairs and Energy) (03ET1205G)
  • Department of Energy | National Renewable Energy Laboratory, Office of Energy Efficiency and Renewable Energy (NREL) (AC36-08GO28308)
Topics
  • Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
  • Physical Sciences › Materials Science › Metals and Alloys › Extraction and Separation Processes
Keywords
lithium iron phosphate batteries, battery degradation modeling, temperature-dependent degradation, capacity fade, calendar aging, cycle aging, battery lifetime prediction, semi-empirical model, stationary energy storage

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