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Large Scaled Synthesis of Heterostructured Electrospun TiO2/SnO2Nanofibers with an Enhanced Photocatalytic Activity
Open accessAbstract
Heterostructured TiO 2 /SnO 2 fibrillar nanocomposites were synthesized by using electrospinning technology with the setup composed of a syringe pump with two parallel syringes on it and a rotating collector. The heterojunctions were formed between TiO 2 and SnO 2 nanofibers fast and efficiently on a large scale, after the fiberizing carrier polyvinylpyrrolidone (PVP) on the as-spun composite nanofibers was burnt away at 500°C. The samples were characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflection spectroscopy (DRS), and photoluminescence spectra (PL), respectively. The results indicated that two kinds of small nanofibers with different diameters were interconnected to form heterojunctions. Photocatalytic tests displayed that the heterostructured TiO 2 /SnO 2 nanofibers exhibited a much higher degradation rate of methylene blue (MB), rhodamine B (RhB), and 4-chlorophenol (4-CP) than that of bare TiO 2 nanofibers or Evonik P25 under UV light irradiation. The enhanced photocatalytic activity could be attributed to the effective charge separation derived from the coupling effect of TiO 2 and SnO 2 nanocomposites.
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Environmental applications of semiconductor photocatalysis
Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W. (1995) · Chemical Reviews · doi:10.1021/cr00033a004 · Cited by 18,495
Xiang, Q., Yu, J., & Jaroniec, M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302846n · Cited by 2,360
Cited by
Pirhashemi, M., Habibi-Yangjeh, A., & Rahim Pouran, S. (2018) · Journal of Industrial and Engineering Chemistry · doi:10.1016/j.jiec.2018.01.012 · Cited by 847
Electrically conductive polymer composites for smart flexible strain sensors: a critical review
Liu, H., Li, Q., Zhang, S., Yin, R., Liu, X., He, Y., Dai, K., Shan, C., Guo, J., Liu, C., et al. (2018) · Journal of Materials Chemistry C · doi:10.1039/c8tc04079f · Cited by 709
Self-citationKaur, R., Kaur, A., Umar, A., Anderson, W. A., & Kansal, S. K. (2019) · Materials Research Bulletin · doi:10.1016/j.materresbull.2018.07.025 · Cited by 292
Metadata
- Authors
- Zhang, L., Yu, W., Han, C., Guo, J., Zhang, Q., Xie, H., Shao, Q., Sun, Z., & Guo, Z.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2017
- Volume
- 164
- Issue
- 9
- Pages
- H651-H656
- ISSN
- 0013-4651 (ISSN-L)
- 1945-7111
- OpenAlex
- W2737770957
- Cited by
- 287
- References
- 2
- FWCI
- 16.37
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Zhang, L., Yu, W., Han, C., Guo, J., Zhang, Q., Xie, H., Shao, Q., Sun, Z., & Guo, Z. (2017). Large Scaled Synthesis of Heterostructured Electrospun TiO2/SnO2Nanofibers with an Enhanced Photocatalytic Activity. Journal of The Electrochemical Society. https://doi.org/10.1149/2.1531709jes
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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