Polyvinyl chloride Waste as an Adsorbent for the Sorption ofPb2+from Aqueous Solution
Open accessAbstract
The sorption of Pb2+from solution by polyvinyl chloride waste was investigated. The morphological features of the polymer sample were studied using the energy dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), X-ray diffraction spectroscopy (XRD), and the Fourier transform infrared spectroscopy (FTIR). Equilibrium, kinetic, and thermodynamic batch adsorption experiments were carried out by the concentration, time, and temperature effects, respectively. The morphological image of the polymer showed irregular small size particles which indicated a high surface area and porosity that facilitated sorption. The adsorption studies recorded relatively rapid uptake of Pb2+by the polymer which was mainly diffusion controlled and followed a second order kinetic process. The thermodynamic studies suggested relatively low temperature (low energy) favoured sorption which was exothermic with a physisorption mechanism.
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Polyvinyl chloride (PVC) waste rapidly adsorbs lead ions from wastewater, achieving effective removal (99%) within 5 min at 30 °C.
“Finally, Wankasi et al. [63] demonstrated the rapid adsorption of lead ions from wastewater using polyvinyl chloride (PVC) waste, achieving effective removal (99%) within 5 min at 30 °C.”
From Transforming Plastic Waste into Value: A Review of Management Strategies and Innovative Applications in Sustainable Construction (2025) · cites this paper as [63]
The Results and Discussion report 99% Pb²⁺ removal after 5 minutes and, separately, optimum sorption of 99% at 30 °C. The study describes batch tests in aqueous solution, not wastewater, and does not establish that the 5-minute result was obtained at 30 °C. (LLM, conf=0.88)
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Cites
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Transforming Plastic Waste into Porous Carbon for Capturing Carbon Dioxide: A Review
Hussin, F., Aroua, M. K., Kassim, M. A., & Md. Ali, U. F. (2021) · Energies · doi:10.3390/en14248421 · Cited by 84 · see citing works
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- Authors
- Wankasi, D., & Dikio, E. D.
- Affiliations
- Vaal University of Technology (ZA)
- Corresponding author
- Dikio, Ezekiel Dixon
- ORCID
- Dikio, Ezekiel Dixon
- Venue
- Journal of Chemistry
- Publisher
- Wiley
- Published
- 2014
- Volume
- 2014
- Pages
- 1-7
- ISSN
- 2090-9063 (ISSN-L)
- 2090-9071
- OpenAlex
- W2088618212
- Cited by
- 24
- References
- 7
- Citations by year
- 2026: 2 · 2025: 2 · 2023: 2 · 2022: 4 · 2021: 7 · 2020: 1 · 2019: 1 · 2017: 1 · 2016: 2 · 2015: 2
- FWCI
- 1.26
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Locations
- Journal of Chemistry (publishedVersion, cc-by)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
- Funders
- National IT Industry Promotion Agency
- Vaal University of Technology
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Engineering › Mechanical Engineering › Extraction and Separation Processes
- Keywords
- polyvinyl chloride waste, lead ion removal, low-cost adsorbent, heavy metal adsorption, adsorption kinetics, adsorption thermodynamics, physisorption, diffusion-controlled adsorption, second-order kinetics, aqueous solution treatment
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