Cited by 24Adsorption and biosorption for pollutant removalEnvironmental remediation with nanomaterialsExtraction and Separation Processes

Polyvinyl chloride Waste as an Adsorbent for the Sorption ofPb2+from Aqueous Solution

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Wankasi, Donbebe, Dikio, Ezekiel Dixon·2014·Journal of Chemistry

Abstract

The sorption of Pb2+from solution by polyvinyl chloride waste was investigated. The morphological features of the polymer sample were studied using the energy dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), X-ray diffraction spectroscopy (XRD), and the Fourier transform infrared spectroscopy (FTIR). Equilibrium, kinetic, and thermodynamic batch adsorption experiments were carried out by the concentration, time, and temperature effects, respectively. The morphological image of the polymer showed irregular small size particles which indicated a high surface area and porosity that facilitated sorption. The adsorption studies recorded relatively rapid uptake of Pb2+by the polymer which was mainly diffusion controlled and followed a second order kinetic process. The thermodynamic studies suggested relatively low temperature (low energy) favoured sorption which was exothermic with a physisorption mechanism.

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Crossref · 10.1155/2014/817527

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  • Polyvinyl chloride (PVC) waste rapidly adsorbs lead ions from wastewater, achieving effective removal (99%) within 5 min at 30 °C.

    “Finally, Wankasi et al. [63] demonstrated the rapid adsorption of lead ions from wastewater using polyvinyl chloride (PVC) waste, achieving effective removal (99%) within 5 min at 30 °C.”

    From Transforming Plastic Waste into Value: A Review of Management Strategies and Innovative Applications in Sustainable Construction (2025) · cites this paper as [63]

    The Results and Discussion report 99% Pb²⁺ removal after 5 minutes and, separately, optimum sorption of 99% at 30 °C. The study describes batch tests in aqueous solution, not wastewater, and does not establish that the 5-minute result was obtained at 30 °C. (LLM, conf=0.88)

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Cites

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Research works printed but not linked: 5

  1. O. A. Tasie, Basic Plastic Materials and Technology, Adyudo Press, Owerri, Nigeria, 2010.
  2. D. Wankasi, Kinetics of phytosorption of heavy metals using unmodified and modified biomass Nipa palm (Nypa fruticans wurmb) [Ph.D. thesis], University of Port Harcourt, Port Har- court, Nigeria, 2004.
  3. V. J. P. Poots, G. McKay, and J. J. Healy, "Removal of basic dye from effluent using wood as an adsorbent, " Journal of the Water Pollution Control Federation, vol. 50, no. 5, pp. 926-935, 1978.
  4. D. Wankasi, M. Horsfall, and A. I. Spiff, "Measure of sorption efficiency of the petiole biomass of nypa fruticans wurmb for metal ions, " Chemical Technology, vol. 4, pp. 54-60, 2006.
  5. M. Suzuki, Adsorption Engineering, Elsevier, Amsterdam, The Netherlands, 1998.

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Authors
Wankasi, D., & Dikio, E. D.
Affiliations
Vaal University of Technology (ZA)
Corresponding author
Dikio, Ezekiel Dixon
Venue
Journal of Chemistry
Publisher
Wiley
Published
2014
Volume
2014
Pages
1-7
ISSN
  • 2090-9063 (ISSN-L)
  • 2090-9071
OpenAlex
W2088618212
Cited by
24
References
7
Citations by year
2026: 2 · 2025: 2 · 2023: 2 · 2022: 4 · 2021: 7 · 2020: 1 · 2019: 1 · 2017: 1 · 2016: 2 · 2015: 2
FWCI
1.26
Type
journal article
Language
en
Open access
Locations
  • Journal of Chemistry (publishedVersion, cc-by)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
Funders
  • National IT Industry Promotion Agency
  • Vaal University of Technology
Topics
  • Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
  • Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
  • Physical Sciences › Engineering › Mechanical Engineering › Extraction and Separation Processes
Keywords
polyvinyl chloride waste, lead ion removal, low-cost adsorbent, heavy metal adsorption, adsorption kinetics, adsorption thermodynamics, physisorption, diffusion-controlled adsorption, second-order kinetics, aqueous solution treatment

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