The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Processing and characterization of new thermoset nanocomposites based on cellulose whiskers
Abstract
In the present study, the processing and the mechanical properties of new thermoset nanocomposites prepared from aqueous suspensions of microcrystalline cellulose fillers and epoxy are described. The nature of cellulose fibers, which display a large aspect ratio and the ability to associate by means of H-bonds implies that the processing method chosen in this study avoids the problem of a high level of viscosity of the epoxy reactive system-whiskers mixture. The reinforcing effect of this type of natural fiber in an epoxy matrix is mainly shown from the dynamic mechanical properties in the rubbery state. This unusual reinforcement is due to (i) the strong interactions existing between the cellulose whiskers and the epoxy network and, (ii) the creation of a percolating network linked by H-bonds between cellulose fibers. The existence of such a percolation effect is evidenced from the analysis of the rubbery shear modulus of nanocomposites based on various volume fractions of whiskers with mechanical modeling such as Halpin-Kardos and percolation approaches.
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Citations
Cites
Polymer nanocomposites reinforced by cellulose whiskers
Favier, V., Chanzy, H., & Cavaille, J. Y. (1995) · Macromolecules · doi:10.1021/ma00122a053 · Cited by 1,149
Application of equivalent model method to dynamic rheo‐optical properties of crystalline polymer
Takayanagi, M., Uemura, S., & Minami, S. (1964) · Journal of Polymer Science Part C: Polymer Symposia · doi:10.1002/polc.5070050111 · Cited by 323
Cited by
Cellulose nanocrystals: chemistry, self-assembly, and applications
Habibi, Y., Lucia, L. A., & Rojas, O. J. (2010) · Chemical Reviews · doi:10.1021/cr900339w · Cited by 5,980
Cellulosic nanocomposites: a review
(2008) · BioResources · doi:10.15376/biores.3.3.929-980 · Cited by 901
Fortunati, E., Armentano, I., Zhou, Q., Iannoni, A., Saino, E., Visai, L., Berglund, L. A., & Kenny, J. M. (2012) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2011.09.066 · Cited by 581
Preparation of homogeneous dispersions of tunicate cellulose whiskers in organic solvents
van den Berg, O., Capadona, J. R., & Weder, C. (2007) · Biomacromolecules · doi:10.1021/bm061104q · Cited by 278
Rapidly switchable water-sensitive shape-memory cellulose/elastomer nano-composites
Zhu, Y., Hu, J., Luo, H., Young, R. J., Deng, L., Zhang, S., Fan, Y., & Ye, G. (2012) · Soft Matter · doi:10.1039/c2sm07035a · Cited by 208
Metadata
- Authors
- Matos Ruiz, M., Cavaillé, J. Y., Dufresne, A., Gérard, J. F., & Graillat, C.
- Venue
- Composite Interfaces
- Publisher
- Informa UK Limited
- Published
- 2000-01
- Volume
- 7
- Issue
- 2
- Pages
- 117-131
- ISSN
- 0927-6440 (ISSN-L)
- 1568-5543
- OpenAlex
- W2015142886
- Cited by
- 172
- References
- 2
- FWCI
- 2.40
- Type
- journal article
- Language
- en
- Open access
- closed
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- Matos Ruiz, M., Cavaillé, J. Y., Dufresne, A., Gérard, J. F., & Graillat, C. (2000). Processing and characterization of new thermoset nanocomposites based on cellulose whiskers. Composite Interfaces. https://doi.org/10.1163/156855400300184271
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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