Controlling exchange bias in Fe3O4/FeO composite particles prepared by pulsed laser irradiation
Open accessAbstract
Spherical iron oxide nanocomposite particles composed of magnetite and wustite have been successfully synthesized using a novel method of pulsed laser irradiation in ethyl acetate. Both the size and the composition of nanocomposite particles are controlled by laser irradiation condition. Through tuning the laser fluence, the Fe 3 O 4/FeO phase ratio can be precisely controlled, and the magnetic properties of final products can also be regulated. This work presents a successful example of the fabrication of ferro (ferri) (FM)/antiferromagnetic (AFM) systems with high chemical stability. The results show this novel simple method as widely extendable to various FM/AFM nanocomposite systems.
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Wang et al. developed spherical NPs of various MOs, including CuO, Fe2O3/FeO, Co3O4, NiO, WO3, and ZnO through PLI at λ = 355 and 532 nm by an Nd:YAG laser.
“Wang et al. developed spherical NPs of various MOs, including CuO, Fe2O3/FeO, Co3O4, NiO, WO3, and ZnO through PLI at λ = 355 and 532 nm by an Nd:YAG laser140,144.”
From Fundamentals and comprehensive insights on pulsed laser synthesis of advanced materials for diverse photo- and electrocatalytic applications (2022) · cites this paper as [144]
The Introduction and Results and discussion describe spherical Fe3O4/FeO particles made by pulsed laser irradiation, and the Experimental section specifies a 355 nm Nd:YAG laser (pages unavailable in our copy). The paper does not report making the other listed oxides or using 532 nm; it identifies the iron-oxide composite as Fe3O4/FeO, not Fe2O3/FeO. (LLM, conf=0.90)
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Cheng, Y., Zhang, X., Li, L. Y., Wang, C. H., Luo, X., Liu, H., Wang, W. H., & Zheng, R. (2013) · Applied Physics Letters · doi:10.1063/1.4804426
First-Principles Calculations on the Half-Metallicity of Rock-Salt Ferromagnetic FeO
Liu, J., Yang, X., & Kang, W. (2015) · Journal of Materials Science and Chemical Engineering · doi:10.4236/msce.2015.39001
Jena, S. K., Mishra, D. K., Sheppard, C. J., Prinsloo, A. R. E., Behera, D., Mohanty, P., Rana, S., & Mallick, P. (2022) · Journal of Materials Science Materials in Electronics · doi:10.1007/s10854-022-08668-x
Interfacial structure and magnetic coupling at Fe3O4/FeO (001) and (111) interfaces
Sun, Z., Chen, S., Jiang, Y., Yao, T., Gao, C., Chen, C., Ma, X., & Ye, H. (2024) · Physical review. B./Physical review. B · doi:10.1103/physrevb.109.094405
Field-free topological spin textures enable spin selectivity for spin light-emitting diodes
Wei, Y., Cao, S., Zhang, C., Wang, X., Ren, S., Li, H., Yang, Y., Zhou, J., Chen, M., Wu, S., et al. (2025) · 中国科学通报:英文版 · doi:10.1016/j.scib.2025.11.009
FUJIWARA, R., Kozawa, T., Satoshi, O. T. A., Kawashita, M., & Abe, H. (2026) · Journal of Smart Processing · doi:10.7791/jspmee.15.133
- Authors
- Swiatkowska-Warkocka, Z., Kawaguchi, K., Wang, H., Katou, Y., & Koshizaki, N.
- Affiliations
- National Institute of Advanced Industrial Science and Technology (JP)
- Venue
- Nanoscale Research Letters
- Published
- 2011-03-16
- Volume
- 6
- Issue
- 1
- Pages
- 226-226
- ISSN
- 1556-276X (ISSN-L)
- PMC
- PMC3211284
- OpenAlex
- W2126542845
- Cited by
- 71
- References
- 29
- Citations by year
- 2026: 1 · 2025: 4 · 2024: 6 · 2023: 2 · 2022: 8 · 2021: 3 · 2020: 7 · 2019: 7 · 2018: 4 · 2017: 9 · 2016: 3 · 2015: 4 · 2014: 2 · 2013: 4 · 2012: 6
- FWCI
- 2.04
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Nanoscale Research Letters (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- Funders
- National Institute of Advanced Industrial Science and Technology
- Japan Society for the Promotion of Science (2008734)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Magnetic Properties and Synthesis of Ferrites
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Biology › Geomagnetism and Paleomagnetism Studies
- Physical Sciences › Engineering › Biomedical Engineering › Characterization and Applications of Magnetic Nanoparticles
- Keywords
- exchange bias, magnetite, wüstite, pulsed laser irradiation, laser fluence, iron oxide nanoparticles, magnetic properties, chemical stability
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