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Cationic Polymerizations
Abstract
Fundamentals of the reactions of carbocations with nucleophiles mechanistic aspects of cationic polymerization of alkenes controlled/living carbocationic polymerization controlled polymer synthesis by cationic polymerization cationic polymerization of heterocyclics step-growth electrophilic oligomerization and polymerization reactions industrial cationic polymerizations - an overview.
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“The three membered ring has considerable ring strain (115 kJ mol -1 ) [2]”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
In the citing paper
“the ring strain for oxiranes [2] is 116 kJ mol -1”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
In the citing paper
“Rings composed of 3 -8 atoms may polymerize due to the loss of enthalpy associated with the loss of ring strain.”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
In the citing paper
“These compounds require a coinitiator (activator), e.g., an alkyl halide or water, in order to polymerize heterocyclic monomers [2,38,60].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
In the citing paper
“Sulfoniumand iodonium-salts have achieved industrial importance as cationic photo initiators [39].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [39]
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“However, it was later realized that since the reactivities of carbocations are much higher than those of carbanions, the exchange reactions were too slow relative to propagation to achieve narrow MWD and controlled MW [6].”
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Metadata
- Venue
- CRC Press eBooks
- Publisher
- CRC Press
- Published
- 1996-04-26
- OpenAlex
- W625995254
- Cited by
- 426
- References
- 0
- Citations by year
- 2026: 3 · 2025: 10 · 2024: 8 · 2023: 6 · 2022: 4 · 2021: 11 · 2020: 13 · 2019: 11 · 2018: 16 · 2017: 11 · 2016: 7 · 2015: 12 · 2014: 11 · 2013: 19 · 2012: 19
- Type
- reference entry
- Language
- en
- Open access
- closed
- Locations
- CRC Press eBooks (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemistry › Organic Chemistry › Organic and Inorganic Chemical Reactions
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Keywords
- cationic polymerization, carbocations, nucleophilic addition, reaction mechanism, living polymerization, controlled polymerization, step-growth polymerization, industrial polymerization
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