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Cationic Polymerizations
Abstract
Fundamentals of the reactions of carbocations with nucleophiles mechanistic aspects of cationic polymerization of alkenes controlled/living carbocationic polymerization controlled polymer synthesis by cationic polymerization cationic polymerization of heterocyclics step-growth electrophilic oligomerization and polymerization reactions industrial cationic polymerizations - an overview.
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“The three membered ring has considerable ring strain (115 kJ mol -1 ) [2]”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
In the citing paper
“the ring strain for oxiranes [2] is 116 kJ mol -1”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
In the citing paper
“Rings composed of 3 -8 atoms may polymerize due to the loss of enthalpy associated with the loss of ring strain.”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
In the citing paper
“These compounds require a coinitiator (activator), e.g., an alkyl halide or water, in order to polymerize heterocyclic monomers [2,38,60].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [2]
In the citing paper
“Sulfoniumand iodonium-salts have achieved industrial importance as cationic photo initiators [39].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [39]
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Metadata
- Venue
- CRC Press eBooks
- Publisher
- CRC Press
- Published
- 1996-04-26
- OpenAlex
- W625995254
- Cited by
- 426
- References
- 0
- Citations by year
- 2026: 3 · 2025: 10 · 2024: 8 · 2023: 6 · 2022: 4 · 2021: 11 · 2020: 13 · 2019: 11 · 2018: 16 · 2017: 11 · 2016: 7 · 2015: 12 · 2014: 11 · 2013: 19 · 2012: 19
- Type
- reference entry
- Language
- en
- Open access
- closed
- Locations
- CRC Press eBooks (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemistry › Organic Chemistry › Organic and Inorganic Chemical Reactions
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Keywords
- cationic polymerization, carbocations, nucleophilic addition, reaction mechanism, living polymerization, controlled polymerization, step-growth polymerization, industrial polymerization
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