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Phase Transitions and Critical Phenomena
Abstract
Phase transitions may be classied into several dierent types on the basis of the behavior with temperature of the thermodynamic potentials and the order parameter. e order parameter may change discontinuously or continuously at the transition point. In the thermodynamic description of phase transitions, the Helmholtz potential F (constant V) and the Gibbs potential G (constant P) play important roles. A scheme on the basis of the behavior of F or G in the vicinity of the transition point has been developed for the classication of phase transitions as continuous or discontinuous and is discussed in Section 9.3. Figure 9.1 shows a representative phase diagram in the P-T plane for a single component system.
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Cited by
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Amaral, L. A. N., Scala, A., Barthélémy, M., & Stanley, H. E. (2000) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.200327197 · Cited by 3,051
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Metadata
- Venue
- Statistical and Thermal Physics
- Publisher
- CRC Press
- Published
- 2016-04-19
- Pages
- 199-222
- OpenAlex
- W1540380506
- Cited by
- 11,176
- References
- 0
- FWCI
- 245.51
- Type
- book chapter
- Language
- en
- Open access
- closed
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