Thermogravimetric analysis
Abstract
Thermogravimetric analysis (TGA) is a widely applied technique in the field of cement science. Measurements of bound water and portlandite content by TGA are often used to follow the reaction of portland cement or to evaluate the reactivity of supplementary cementitious materials (SCMs), such as fly ash and blast furnace slags. TGA is able to identify X-ray amorphous hydrates, such as C-S-H or AH3, and can be used complementarily to other techniques such as X-ray diffraction (XRD).
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TGA indicates the presence of C-(N-)A-S-H, with a broad mass loss at approximately 100 °C, and AFm phases such as strätlingite, hemicarbonate, and/or hydrotalcite, as evidenced by the shoulder at 180 °C.
“TGA indicates the presence of C-(N-)A-S-H, with a broad mass loss at approximately 100 °C, and AFm phases such as strätlingite, hemicarbonate, and/or hydrotalcite, as evidenced by the shoulder at 180 °C 46,47 .”
From Thermodynamic Modeling and Experimental Study of Carbonation of Alkali-Activated Slag Cements (2023) · cites this paper as [47]
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Thermodynamic Modeling and Experimental Study of Carbonation of Alkali-Activated Slag Cements
Park, S., Lothenbach, B., Jang, J. G., Kim, H.-K., & Lee, N. (2023) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.2c05789 · Cited by 43 · see citing works
X-ray Total Scattering Study of Phases Formed from Cement Phases Carbonation
Cuesta, A., De la Torre, A. G., & Aranda, M. A. G. (2021) · Minerals · doi:10.3390/min11050519 · Cited by 14 · see citing works
- Authors
- BARBARA LOTHENBACH, P. D. A. K. D. W.
- Corresponding author
- BARBARA LOTHENBACH, PAWEŁ DURDZIŃSKI AND KLAARTJE DE WEERDT
- Venue
- A Practical Guide to Microstructural Analysis of Cementitious Materials
- Publisher
- CRC Press
- Published
- 2018-10-09
- Pages
- 196-231
- OpenAlex
- W4236959610
- Cited by
- 29
- References
- 0
- Citations by year
- 2026: 5 · 2025: 11 · 2024: 4 · 2022: 1 · 2021: 2 · 2019: 2 · 2018: 2 · 2016: 1 · 2015: 1
- FWCI
- 5.94
- Type
- book chapter
- Language
- en
- Open access
- closed
- Locations
- CRC Press eBooks (publishedVersion)
- Topics
- Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
- Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
- Physical Sciences › Engineering › Civil and Structural Engineering › Concrete Properties and Behavior
- Keywords
- thermogravimetric analysis, bound water, portlandite, Portland cement, supplementary cementitious materials, fly ash, blast furnace slag, calcium silicate hydrate, cement reactivity
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