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Mechanoelectric effects in ionic gels
Open accessAbstract
Certain fluorinated ion-exchange membranes, when swollen and suitably plated by conducting electrodes, display a spontaneous curvature increasing with the applied electric field E (1) . There is also an inverse effect, where an imposed curvature induces an electric field (in open circuit conditions). We present here a compact description of these effects in the linear regime, and in static conditions: this is based on linear irreversible thermodynamics, with two driving forces ( E and a water pressure gradient ∇ p ) and two fluxes (electric current and water current). We also give some qualitative estimates of the three Onsager coefficients which come into play.
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Citations
Cited by
Ionic polymer–metal composites: IV. Industrial and medical applications
Shahinpoor, M., & Kim, K. J. (2005) · Smart Materials and Structures · doi:10.1088/0964-1726/14/1/020 · Cited by 614
Self-citationIonic polymer metal composites: II. Manufacturing techniques
Kim, K. J., & Shahinpoor, M. (2003) · Smart Materials and Structures · doi:10.1088/0964-1726/12/1/308 · Cited by 584
Self-citationRecent advances in ionic polymer–metal composite actuators and their modeling and applications
Jo, C., Pugal, D., Oh, I.-K., Kim, K. J., & Asaka, K. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2013.04.003 · Cited by 406
Self-citationShahinpoor, M., & Kim, K. J. (2004) · Smart Materials and Structures · doi:10.1088/0964-1726/13/6/009 · Cited by 379
Self-citationThe state of understanding of ionic polymer metal composite architecture: a review
Tiwari, R., & Garcia, E. (2011) · Smart Materials and Structures · doi:10.1088/0964-1726/20/8/083001 · Cited by 189
Metadata
- Authors
- Gennes, P. G. D., Okumura, K., Shahinpoor, M., & Kim, K. J.
- Venue
- Europhysics Letters (EPL)
- Publisher
- IOP Publishing
- Published
- 2000-05-15
- Volume
- 50
- Issue
- 4
- Pages
- 513-518
- ISSN
- 0295-5075 (ISSN-L)
- 1286-4854
- OpenAlex
- W2059008183
- Cited by
- 333
- References
- 0
- FWCI
- 8.76
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Gennes, P. G. D., Okumura, K., Shahinpoor, M., & Kim, K. J. (2000). Mechanoelectric effects in ionic gels. Europhysics Letters (EPL). https://doi.org/10.1209/epl/i2000-00299-3
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