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Gradient of glass transition temperature in filled elastomers
Open accessAbstract
By studying model systems consisting of poly(ethyl acrylate) polymer chains covalently bound to silica particles, we show here how the temperature dependence of the modulus of filled elastomers can be explained by a long-ranged gradient of the polymer matrix glass transition temperature in the vicinity of the particles. We are led to this conclusion by comparing NMR and mechanical data. We show thereby that the mechanisms of reinforcement are the same as those which lead to an increase of the glass transition temperature of strongly adsorbed thin polymer films. It allows us in particular to propose a new time-temperature superposition law for the filled elastomers viscoelasticity.
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Cited by
Shape and temperature memory of nanocomposites with broadened glass transition
Miaudet, P., Derré, A., Maugey, M., Zakri, C., Piccione, P. M., Inoubli, R., & Poulin, P. (2007) · Science · doi:10.1126/science.1145593 · Cited by 416
Molecular dynamics simulations of glassy polymers
Barrat, J.-L., Baschnagel, J., & Lyulin, A. (2010) · Soft Matter · doi:10.1039/b927044b · Cited by 320
Robertson, C. G., Lin, C. J., Rackaitis, M., & Roland, C. M. (2008) · Macromolecules · doi:10.1021/ma7022364 · Cited by 316
Merabia, S., Sotta, P., & Long, D. R. (2008) · Macromolecules · doi:10.1021/ma8014728 · Cited by 284
Self-citationLow-field NMR investigations of nanocomposites: Polymer dynamics and network effects
Papon, A., Saalwächter, K., Schäler, K., Guy, L., Lequeux, F., & Montes, H. (2011) · Macromolecules · doi:10.1021/ma102486x · Cited by 267
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Metadata
- Authors
- Berriot, J., Montes, H., Lequeux, F., Long, D., & Sotta, P.
- Venue
- Europhysics Letters (EPL)
- Publisher
- IOP Publishing
- Published
- 2003-10
- Volume
- 64
- Issue
- 1
- Pages
- 50-56
- ISSN
- 0295-5075 (ISSN-L)
- 1286-4854
- OpenAlex
- W1987023965
- Cited by
- 184
- References
- 0
- FWCI
- 3.18
- Type
- journal article
- Language
- en
- Open access
- bronze
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