Shape and temperature memory of nanocomposites with broadened glass transition
Abstract
Shape-memory polymers can revert to their original shape when they are reheated. The stress generated by shape recovery is a growing function of the energy absorbed during deformation at a high temperature; thus, high energy to failure is a necessary condition for strong shape-memory materials. We report on the properties of composite nanotube fibers that exhibit this particular feature. We observed that these composites can generate a stress upon shape recovery up to two orders of magnitude greater than that generated by conventional polymers. In addition, the nanoparticles induce a broadening of the glass transition and a temperature memory with a peak of recovery stress at the temperature of their initial deformation.
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The temperature-memory effect approach has been largely employed to achieve multiple-way SMPs with a broad glass transition or a broad melting transition as the switching transition.
“Such an approach has been largely employed to achieve multiple-way SMPs with a broad glass transition [82-92] and a broad melting transition [93-95] as the switching transition.”
From Two-Way and Multiple-Way Shape Memory Polymers for Soft Robotics: An Overview (2020) · cites this paper as [82]
Miaudet et al. achieved the highest recovery stress of shape memory polymer composites; the maximal stress generated by a carbon nanotube/polyvinyl alcohol fiber reached 150 MPa, two orders of magnitude higher than that of neat shape memory polymers.
“Among all the outstanding achievements, Miaudet et al. [290] achieved the highest recovery stress of SMPCs.The maximal stress generated by a CNT/polyvinyl alcohol fiber reached 150 MPa which is two orders of magnitude higher than that of neat SMPs.”
From A review of stimuli-responsive shape memory polymer composites (2013) · cites this paper as [290]
Miaudet et al. achieved the highest recovery stress of SMPCs; the maximal stress generated by a CNT/polyvinyl alcohol fiber reached 150 MPa, which is two orders of magnitude higher than that of neat SMPs.
“Among all the outstanding achievements, Miaudet et al. [290] achieved the highest recovery stress of SMPCs.The maximal stress generated by a CNT/polyvinyl alcohol fiber reached 150 MPa which is two orders of magnitude higher than that of neat SMPs.”
From A review of stimuli-responsive shape memory polymer composites (2013) · cites this paper as [290]
In PVA/CNTs fibrous membranes, nanotubes induced a broadening of the Tg and a temperature memory with a peak of recovery stress at the temperature of their initial deformation.
“For example in the case of fibrous membranes from poly(vinyl alcohol) (PVA)/CNTs the nanotubes induced a broadening of the Tg and a temperature memory with a peak of recovery stress at the temperature of their initial deformation.”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [114]
The generated stress upon shape recovery was up to two orders of magnitude greater than that characteristic for conventional polymers.
“Interestingly, the generated stress upon shape recovery was up to two orders of magnitude greater than that one characteristic for the conventional polymers [114].”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [114]
Miaudet et al. reported a temperature memory effect: a stress recovery peak under constrained conditions was observed at the temperature where a polymer had been initially deformed, as evidenced for PVA/CNT composites.
“Further insights came from Miaudet et al. [189], who reported on the so-called “temperature memory effect” (TME), which means that a stress recovery peak under constrained conditions was observed at that temperature, where a polymer had been initially deformed, as evidenced for composites made from poly(vinyl alcohol) (PVA) and carbon nanotubes (CNTs).”
From Review on the Functional Determinants and Durability of Shape Memory Polymers (2010) · cites this paper as [189]
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- Authors
- Miaudet, P., Derré, A., Maugey, M., Zakri, C., Piccione, P. M., Inoubli, R., & Poulin, P.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Centre de Recherche Paul Pascal–CNRS, Université Bordeaux I, 115 Avenue Schweitzer, F-33600 Pessac, France.
- Corresponding author
- Poulin, Philippe
- Venue
- Science
- Published
- 2007-11-23
- Volume
- 318
- Issue
- 5854
- Pages
- 1294-1296
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2002513249
- Cited by
- 416
- References
- 29
- Citations by year
- 2026: 4 · 2025: 18 · 2024: 20 · 2023: 17 · 2022: 15 · 2021: 22 · 2020: 19 · 2019: 27 · 2018: 16 · 2017: 28 · 2016: 34 · 2015: 31 · 2014: 32 · 2013: 26 · 2012: 27
- FWCI
- 34.32
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Oskar-Bordeaux (Universite de Bordeaux) (submittedVersion)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Materials Science › Materials Chemistry › Material Dynamics and Properties
- Keywords
- shape memory polymers, nanocomposites, carbon nanotube fibers, energy to failure, polymer nanocomposites
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