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Silicic Acid Polymerization Catalyzed by Amines and Polyamines

Mizutani, Tadashi, Nagase, Hisato, Fujiwara, Naohiko, Ogoshi, Hisanobu·1998·Bulletin of the Chemical Society of Japan

Abstract

Amines, particularly polyamines, catalyzed the polycondensation of silicic acid in water. The resultant gel contained these polyamines with a N/Si molar ratio of up to 0.5. IR and powder X-ray studies showed that silica gel and polyamines are hybridized at a molecular level through hydrogen bonding. The gel adsorbed anionic dyes from water, whereas normal silica gel adsorbs cationic dyes. Induced CD was observed for the indigo carmine adsorbed on silica gel–poly(l-lysine) hybrid, showing that the hybrid provides a chiral environment to the adsorbate.

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Metadata

Authors
Mizutani, T., Nagase, H., Fujiwara, N., & Ogoshi, H.
Venue
Bulletin of the Chemical Society of Japan
Published
1998-08-01
Volume
71
Issue
8
Pages
2017-2022
ISSN
  • 0009-2673 (ISSN-L)
  • 1348-0634
OpenAlex
W2003762296
Cited by
175
References
0
FWCI
1.82
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Silicic Acid Polymerization Catalyzed by Amines and Polyamines. https://app.cochat.ai/papers/10.1246/bcsj.71.2017
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Mizutani, T., Nagase, H., Fujiwara, N., & Ogoshi, H. (1998). Silicic Acid Polymerization Catalyzed by Amines and Polyamines. Bulletin of the Chemical Society of Japan. https://doi.org/10.1246/bcsj.71.2017

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.