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Gas-liquid chromatographic separation of aldose enantiomers as trimethylsilyl ethers of methyl 2-(polyhydroxyalkyl)-thiazolidine-4(R)-carboxylates.

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HARA, SHUUJI, OKABE, HIKARU, MIHASHI, KUNIHIDE·1987·Chemical and Pharmaceutical Bulletin

Abstract

Pairs of enantiomers of nine aldoses were separated by gas-liquid chromatography on an OV-17 capillary column as the trimethylsilyl ethers of methyl 2- (polyhydroxyalkyl) -thiazolidine-4 (R) -carboxylates, which were obtained by the reaction of aldoses with L-cysteine methyl ester. This method was applied to the determination of the absolute configurations of the component monosaccharides of a Thladiantha saponin.

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Metadata

Authors
HARA, S., OKABE, H., & MIHASHI, K.
Venue
Chemical and Pharmaceutical Bulletin
Published
1987
Volume
35
Issue
2
Pages
501-506
ISSN
  • 0009-2363 (ISSN-L)
  • 1347-5223
OpenAlex
W2001894999
Cited by
545
References
0
FWCI
0.54
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Gas-liquid chromatographic separation of aldose enantiomers as trimethylsilyl ethers of methyl 2-(polyhydroxyalkyl)-thiazolidine-4(R)-carboxylates. https://app.cochat.ai/papers/10.1248/cpb.35.501
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HARA, S., OKABE, H., & MIHASHI, K. (1987). Gas-liquid chromatographic separation of aldose enantiomers as trimethylsilyl ethers of methyl 2-(polyhydroxyalkyl)-thiazolidine-4(R)-carboxylates. Chemical and Pharmaceutical Bulletin. https://doi.org/10.1248/cpb.35.501

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.