Studies on the Essential Oil of Artemisia annua L. III: Discussion on the Structure of Artemisia Ketone
Open accessAbstract
The structure of artemisia ketone had heretofore been represented as 2, 5, 5-trimethyl-1, 6-heptadien-4-one (I), shown in Chart 1, but this was corrected to 2, 5, 5-trimethyl-2, 6-heptadien-4-one (II), as shown in Chart 2. All the reactions could be explained rationally by denying the existence of an isoartemisia-ketone.
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A. annua is a rich source of unusual irregular acyclic monoterpenoids, such as artemisia ketone.
“Phytochemists were interested in A. annua before the discovery of artemisinin because it is a rich source of unusual irregular acyclic monoterpenoids, such as artemisia ketone (276) [115,116,117,118,119,120]”
From The Biosynthesis of Artemisinin (Qinghaosu) and the Phytochemistry of Artemisia annua L. (Qinghao) (2010) · cites this paper as [119]
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The Biosynthesis of Artemisinin (Qinghaosu) and the Phytochemistry of Artemisia annua L. (Qinghao)
Brown, G. D. (2010) · Molecules · doi:10.3390/molecules15117603 · Cited by 363 · see citing works
Li, Y., & Wu, Y. (2010) · Frontiers of Chemistry in China · doi:10.1007/s11458-010-0214-5 · Cited by 20 · see citing works
Terpenoids. IX. Biogenesis of some monoterpenoids not derived from a geranyl precursor
Bates, R. B., & Paknikar, S. K. (1965) · Tetrahedron Letters · doi:10.1016/s0040-4039(00)90088-1 · Cited by 20 · see citing works
Artemisiaketon als Hauptbestandteil des �therischen �les einer neuen Rainfarn-Rasse
Stahl, E., & Scheu, D. (1965) · Die Naturwissenschaften · doi:10.1007/bf00621428 · Cited by 12 · see citing works
THE BIOSYNTHESIS OF A NON-HEAD TO TAIL MONOTERPENE, ARTEMISIA KETONE
Suga, T., Shishibori, T., Kotera, K., & Fujii, R. (1972) · Chemistry Letters · doi:10.1246/cl.1972.533 · Cited by 10 · see citing works
Intramolecular cyclisation of α,β-epoxy-artemisia ketone
Tsankova, E. T., Enev, V. S., & Simova, S. (1984) · Tetrahedron · doi:10.1016/s0040-4020(01)83494-3 · Cited by 5 · see citing works
- Authors
- Takemoto, T., & Nakajima, T.
- Affiliations
- The University of Osaka (JP)
- ORCID
- Nakajima, Tadashi
- Venue
- YAKUGAKU ZASSHI
- Publisher
- Pharmaceutical Society of Japan
- Published
- 1957
- Volume
- 77
- Issue
- 12
- Pages
- 1339-1344
- ISSN
- 0031-6903 (ISSN-L)
- 1347-5231
- OpenAlex
- W2606329058
- Cited by
- 6
- References
- 0
- FWCI
- 0.00
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- YAKUGAKU ZASSHI (publishedVersion)
- Topics
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Cancer Research › Sesquiterpenes and Asteraceae Studies
- Life Sciences › Agricultural and Biological Sciences › Food Science › Essential Oils and Antimicrobial Activity
- Life Sciences › Agricultural and Biological Sciences › Plant Science › Plant chemical constituents analysis
- Keywords
- Artemisia annua, essential oils, artemisia ketone, structure revision, structure elucidation
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