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Terminology for reversible-deactivation radical polymerization previously called "controlled" radical or "living" radical polymerization (IUPAC Recommendations 2010)
Open accessAbstract
This document defines terms related to modern methods of radical polymerization, in which certain additives react reversibly with the radicals, thus enabling the reactions to take on much of the character of living polymerizations, even though some termination inevitably takes place. In recent technical literature, these reactions have often been loosely referred to as, inter alia, "controlled", "controlled/living", or "living" polymerizations. The use of these terms is discouraged. The use of "controlled" is permitted as long as the type of control is defined at its first occurrence, but the full name that is recommended for these polymerizations is "reversible-deactivation radical polymerization".
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Cited by
Controlled/Living Radical Polymerization in Dispersed Systems: An Update
Zetterlund, P. B., Thickett, S. C., Perrier, S., Bourgeat-Lami, E., & Lansalot, M. (2015) · Chemical Reviews · doi:10.1021/cr500625k · Cited by 485
Gregory, A., & Stenzel, M. H. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.08.004 · Cited by 470
Nitroxide-Mediated Radical Polymerization: Limitations and Versatility
Grubbs, R. B. (2011) · Polymer Reviews · doi:10.1080/15583724.2011.566405 · Cited by 398
50th Anniversary Perspective: Living Polymerization—Emphasizing the Molecule in Macromolecules
Grubbs, R. B., & Grubbs, R. H. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01440 · Cited by 396
McKenzie, T. G., Fu, Q., Uchiyama, M., Satoh, K., Xu, J., Boyer, C., Kamigaito, M., & Qiao, G. G. (2016) · Advanced Science · doi:10.1002/advs.201500394 · Cited by 283
Metadata
- Authors
- Jenkins, A. D., Jones, R. G., & Moad, G.
- Venue
- Pure and Applied Chemistry
- Publisher
- Walter de Gruyter GmbH
- Published
- 2009-11-18
- Volume
- 82
- Issue
- 2
- Pages
- 483-491
- ISSN
- 0033-4545 (ISSN-L)
- 1365-3075
- OpenAlex
- W2111469549
- Cited by
- 552
- References
- 0
- FWCI
- 14.21
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Jenkins, A. D., Jones, R. G., & Moad, G. (2009). Terminology for reversible-deactivation radical polymerization previously called "controlled" radical or "living" radical polymerization (IUPAC Recommendations 2010). Pure and Applied Chemistry. https://doi.org/10.1351/pac-rep-08-04-03
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