The DOI matches its Crossref record; 243 of the 243 references it cites were found in a registry or an index.
Nitroxide-Mediated Radical Polymerization: Limitations and Versatility
Abstract
Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP) has been widely adopted for the preparation of a panoply of new polymer architectures. While NMP provides a number of advantages for the preparation of specific types of polymers, several inherent limitations with NMP have led to the more widespread use of other reversible-deactivation radical polymerization (RDRP) methods, chiefly atom transfer radical polymerization (ATRP) and reversible addition-fragmentation-chain transfer (RAFT) polymerization, in polymer synthesis. This short review discusses strategies that have been adopted for dealing with the difficulties of NMP and also surveys the use of NMP to prepare new polymers and copolymers over the past several years.
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Citations
Cites
New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations
Hawker, C. J., Bosman, A. W., & Harth, E. (2001) · Chemical Reviews · doi:10.1021/cr990119u · Cited by 3,850
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Narrow molecular weight resins by a free-radical polymerization process
Georges, M. K., Veregin, R. P. N., Kazmaier, P. M., & Hamer, G. K. (1993) · Macromolecules · doi:10.1021/ma00063a054 · Cited by 2,087
Fischer, H. (2001) · Chemical Reviews · doi:10.1021/cr990124y · Cited by 1,344
Development of a Universal Alkoxyamine for “Living” Free Radical Polymerizations
Benoit, D., Chaplinski, V., Braslau, R., & Hawker, C. J. (1999) · Journal of the American Chemical Society · doi:10.1021/ja984013c · Cited by 1,058
Controlled/living radical polymerization
Matyjaszewski, K., & Spanswick, J. (2005) · Materials Today · doi:10.1016/s1369-7021(05)00745-5 · Cited by 746
Toward Living Radical Polymerization
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Accounts of Chemical Research · doi:10.1021/ar800075n · Cited by 734
Controlled/Living Radical Polymerization in Dispersed Systems
Zetterlund, P. B., Kagawa, Y., & Okubo, M. (2008) · Chemical Reviews · doi:10.1021/cr800242x · Cited by 677
End group removal and modification of RAFT polymers
Willcock, H., & O'Reilly, R. K. (2010) · Polym. Chem. · doi:10.1039/b9py00340a · Cited by 607
Jenkins, A. D., Jones, R. G., & Moad, G. (2009) · Pure and Applied Chemistry · doi:10.1351/pac-rep-08-04-03 · Cited by 552
Cited by
Metal-Free Atom Transfer Radical Polymerization
Treat, N. J., Sprafke, H., Kramer, J. W., Clark, P. G., Barton, B. E., Read de Alaniz, J., Fors, B. P., & Hawker, C. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja510389m · Cited by 939
50th Anniversary Perspective: Living Polymerization—Emphasizing the Molecule in Macromolecules
Grubbs, R. B., & Grubbs, R. H. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01440 · Cited by 396
Self-citationPolymeric Surfactants: Synthesis, Properties, and Links to Applications
Raffa, P., Wever, D. A. Z., Picchioni, F., & Broekhuis, A. A. (2015) · Chemical Reviews · doi:10.1021/cr500129h · Cited by 389
Polymeric Delivery of Therapeutic Nucleic Acids
Kumar, R., Santa Chalarca, C. F., Bockman, M. R., Bruggen, C. V., Grimme, C. J., Dalal, R. J., Hanson, M. G., Hexum, J. K., & Reineke, T. M. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00997 · Cited by 365
Nitroxide-catalyzed transition-metal-free aerobic oxidation processes
Wertz, S., & Studer, A. (2013) · Green Chemistry · doi:10.1039/c3gc41459k · Cited by 323
Metadata
- Authors
- Grubbs, R. B.
- Venue
- Polymer Reviews
- Publisher
- Informa UK Limited
- Published
- 2011-04-22
- Volume
- 51
- Issue
- 2
- Pages
- 104-137
- ISSN
- 0736-6574 (ISSN-L)
- 1558-3724
- 1558-3716
- OpenAlex
- W2014934592
- Cited by
- 398
- References
- 243
- FWCI
- 13.62
- Type
- journal article
- Language
- en
- Open access
- closed
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