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Absorption and intensity-dependent photoluminescence measurements on CdSe quantum dots: assignment of the first electronic transitions

Ekimov, A. I., Kudryavtsev, I. A., Efros, Al. L., Yazeva, T. V., Hache, F., Schanne-Klein, M. C., Rodina, A. V., Ricard, D., Flytzanis, C.·1993·Journal of the Optical Society of America B

Abstract

CdSe is used as a prototype to show the implications of valence-band degeneracy for the optical properties of strongly quantum-confined nanocrystals. Absorption spectra and photoluminescence spectra obtained under intermediate and strong pulsed excitation show the presence of new structures. The energy levels for the electron and the hole are calculated with the spherical confinement, the nonparabolicity of the conduction band, and the valence band degeneracy taken into account. The oscillator strengths of the dipole-allowed transitions are also calculated. This model is found to be in good agreement with the experimental observations, which originate mainly from the quantization of the energy spectrum of holes with due account given to valence-band degeneracy.

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Metadata

Authors
Ekimov, A. I., Kudryavtsev, I. A., Efros, A. L., Yazeva, T. V., Hache, F., Schanne-Klein, M. C., Rodina, A. V., Ricard, D., & Flytzanis, C.
Venue
Journal of the Optical Society of America B
Published
1993-01-01
Volume
10
Issue
1
Pages
100
ISSN
  • 0740-3224 (ISSN-L)
  • 1520-8540
OpenAlex
W2168172744
Cited by
811
References
1
FWCI
28.77
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Absorption and intensity-dependent photoluminescence measurements on CdSe quantum dots: assignment of the first electronic transitions. https://app.cochat.ai/papers/10.1364/josab.10.000100
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Ekimov, A. I., Kudryavtsev, I. A., Efros, A. L., Yazeva, T. V., Hache, F., Schanne-Klein, M. C., Rodina, A. V., Ricard, D., & Flytzanis, C. (1993). Absorption and intensity-dependent photoluminescence measurements on CdSe quantum dots: assignment of the first electronic transitions. Journal of the Optical Society of America B. https://doi.org/10.1364/josab.10.000100

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.