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Absorption and intensity-dependent photoluminescence measurements on CdSe quantum dots: assignment of the first electronic transitions
Abstract
CdSe is used as a prototype to show the implications of valence-band degeneracy for the optical properties of strongly quantum-confined nanocrystals. Absorption spectra and photoluminescence spectra obtained under intermediate and strong pulsed excitation show the presence of new structures. The energy levels for the electron and the hole are calculated with the spherical confinement, the nonparabolicity of the conduction band, and the valence band degeneracy taken into account. The oscillator strengths of the dipole-allowed transitions are also calculated. This model is found to be in good agreement with the experimental observations, which originate mainly from the quantization of the energy spectrum of holes with due account given to valence-band degeneracy.
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Citations
Cites
Motion of Electrons and Holes in Perturbed Periodic Fields
Luttinger, J. M., & Kohn, W. (1955) · Physical Review · doi:10.1103/physrev.97.869 · Cited by 3,088
Cited by
Dabbousi, B. O., Rodriguez-Viejo, J., Mikulec, F. V., Heine, J. R., Mattoussi, H., Ober, R., Jensen, K. F., & Bawendi, M. G. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp971091y · Cited by 4,229
The Electronic Structure of Semiconductor Nanocrystals
Efros, A. L., & Rosen, M. (2000) · Annual Review of Materials Science · doi:10.1146/annurev.matsci.30.1.475 · Cited by 965
Self-citationKambhampati, P. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp2058673 · Cited by 391
Nonlinear refraction and absorption: mechanisms and magnitudes
Christodoulides, D. N., Khoo, I. C., Salamo, G. J., Stegeman, G. I., & Van Stryland, E. W. (2010) · Advances in Optics and Photonics · doi:10.1364/aop.2.000060 · Cited by 342
Surface Plasmon Mediated Strong Exciton−Photon Coupling in Semiconductor Nanocrystals
Gómez, D. E., Vernon, K. C., Mulvaney, P., & Davis, T. J. (2010) · Nano Letters · doi:10.1021/nl903455z · Cited by 314
Metadata
- Authors
- Ekimov, A. I., Kudryavtsev, I. A., Efros, A. L., Yazeva, T. V., Hache, F., Schanne-Klein, M. C., Rodina, A. V., Ricard, D., & Flytzanis, C.
- Venue
- Journal of the Optical Society of America B
- Publisher
- Optica Publishing Group
- Published
- 1993-01-01
- Volume
- 10
- Issue
- 1
- Pages
- 100
- ISSN
- 0740-3224 (ISSN-L)
- 1520-8540
- OpenAlex
- W2168172744
- Cited by
- 811
- References
- 1
- FWCI
- 28.77
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Ekimov, A. I., Kudryavtsev, I. A., Efros, A. L., Yazeva, T. V., Hache, F., Schanne-Klein, M. C., Rodina, A. V., Ricard, D., & Flytzanis, C. (1993). Absorption and intensity-dependent photoluminescence measurements on CdSe quantum dots: assignment of the first electronic transitions. Journal of the Optical Society of America B. https://doi.org/10.1364/josab.10.000100
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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