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Discrimination among Carbonate Minerals by Raman Spectroscopy Using the Laser Microprobe
Abstract
Raman spectroscopy has been used to distinguish the individual carbonate minerals belonging to the calcite, dolomite, and aragonite structural groups. With the use of the in situ laser microprobe technique, it is demonstrated that particle-size effects do not hinder the mineral identification and that high precision in line position is achieved. Spectra can be obtained from samples in any form and provide rapid, nondestructive analyses on a microscopic scale of the hard-to-discriminate carbonate minerals.
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In the citing paper
“Despite these advantages, spectral databases of Raman spectra for carbonates are still limited especially for their solid-solution systems [2, 15, 21–30].”
From Micro-Raman spectroscopic analysis on natural carbonates: linear relations found via biaxial plotting of peak frequencies for cation substituted species (2022) · cites this paper as [21]
In the citing paper
“In the case of single cation carbonates, the substitution of the cation from Ca2+ to Fe2+, Mg2+, or Mn2+ leads to about 30–60 cm−1 of blue shift for T and L modes [2, 21–23].”
From Micro-Raman spectroscopic analysis on natural carbonates: linear relations found via biaxial plotting of peak frequencies for cation substituted species (2022) · cites this paper as [21]
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Metadata
- Authors
- Herman, R. G., Bogdan, C. E., Sommer, A. J., & Simpson, D. R.
- Affiliations
- Lehigh University (US)
- Center for Surface and Coatings Research, Sinclair Laboratory, #7 (R.G.H., C.E.B., A.J.S.), and Department of Geological Sciences (D.R.S.), Lehigh University, Bethlehem, Pennsylvania 18015
- Venue
- Applied Spectroscopy
- Publisher
- SAGE Publications
- Published
- 1987-03
- Volume
- 41
- Issue
- 3
- Pages
- 437-440
- ISSN
- 0003-7028 (ISSN-L)
- 1943-3530
- OpenAlex
- W2160335632
- Cited by
- 130
- References
- 13
- Citations by year
- 2026: 4 · 2025: 3 · 2024: 3 · 2023: 7 · 2022: 5 · 2021: 3 · 2020: 7 · 2019: 3 · 2018: 6 · 2017: 7 · 2016: 3 · 2015: 4 · 2014: 4 · 2013: 6 · 2012: 6
- FWCI
- 1.19
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Applied Spectroscopy (publishedVersion)
- Funders
- U.S. Department of Energy
- Lehigh University
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Mineralogy and Gemology Studies
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Spectroscopy Techniques in Biomedical and Chemical Research
- Social Sciences › Arts and Humanities › Archeology (arts and humanities) › Cultural Heritage Materials Analysis
- Keywords
- carbonate minerals, mineral discrimination, calcite, dolomite, aragonite, Raman spectroscopy, laser microprobe, particle size effects, in situ analysis
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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