Raman spectra of carbonates of calcite structure
Open accessAbstract
Six new Raman spectra of carbonates of calcite structure (D 6 3d ) are presented and compared with the previously reported siderite and calcite spectra. Correction on the assignment of the electronic Raman in siderite was done by this comparative study. In calcite a new line was observed and assigned as an E g +A 1g mode. Some samples were prepared by hydrothermal synthesis and the technique is described.
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In single-cation carbonates, substitution of the cation from Ca2+ to Fe2+, Mg2+, or Mn2+ leads to about 30-60 cm−1 of blue shift for the T and L modes.
“In the case of single cation carbonates, the substitution of the cation from Ca2+ to Fe2+, Mg2+, or Mn2+ leads to about 30–60 cm−1 of blue shift for T and L modes [2, 21–23].”
From Micro-Raman spectroscopic analysis on natural carbonates: linear relations found via biaxial plotting of peak frequencies for cation substituted species (2022) · cites this paper as [23]
Spectral databases of Raman spectra for carbonates are still limited, especially for their solid-solution systems.
“Despite these advantages, spectral databases of Raman spectra for carbonates are still limited especially for their solid-solution systems [2, 15, 21–30].”
From Micro-Raman spectroscopic analysis on natural carbonates: linear relations found via biaxial plotting of peak frequencies for cation substituted species (2022) · cites this paper as [23]
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- Authors
- Rutt, H. N., & Nicola, J. H.
- Affiliations
- Universidade Federal do Rio Grande do Sul (BR)
- ORCID
- Rutt, H N
- Venue
- Journal of Physics C: Solid State Physics
- Publisher
- IOP Publishing
- Published
- 1974-12-21
- Volume
- 7
- Issue
- 24
- Pages
- 4522-4528
- ISSN
- 0022-3719 (ISSN-L)
- OpenAlex
- W2027882865
- Cited by
- 202
- References
- 0
- Citations by year
- 2026: 4 · 2025: 6 · 2024: 11 · 2023: 15 · 2022: 16 · 2021: 8 · 2020: 11 · 2019: 6 · 2018: 18 · 2017: 8 · 2016: 9 · 2015: 6 · 2014: 11 · 2013: 10 · 2012: 9
- FWCI
- 1.13
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Journal of Physics C Solid State Physics (publishedVersion)
- ePrints Soton (University of Southampton) (submittedVersion)
- Funders
- Universidade Federal do Rio Grande do Sul
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Solid-state spectroscopy and crystallography
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Mineralogy and Gemology Studies
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Spectroscopy Techniques in Biomedical and Chemical Research
- Keywords
- Raman spectra, carbonates, calcite structure, siderite, calcite, electronic Raman scattering, vibrational assignment, hydrothermal synthesis, D6h symmetry
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